Exciton formation dynamics and band-like free charge-carrier transport in 2D metal halide perovskite semiconductors

Advanced Functional Materials Wiley 33:32 (2023) 2300363

Authors:

Silvia G Motti, Manuel Kober-Czerny, Marcello Righetto, Philippe Holzhey, Joel Smith, Hans Kraus, Henry J Snaith, Michael B Johnston, Laura M Herz

Abstract:

Metal halide perovskite (MHP) semiconductors have driven a revolution in optoelectronic technologies over the last decade, in particular for high-efficiency photovoltaic applications. Low-dimensional MHPs presenting electronic confinement have promising additional prospects in light emission and quantum technologies. However, the optimisation of such applications requires a comprehensive understanding of the nature of charge carriers and their transport mechanisms. This study employs a combination of ultrafast optical and terahertz spectroscopy to investigate phonon energies, charge-carrier mobilities, and exciton formation in 2D (PEA)2PbI4 and (BA)2PbI4 (where PEA is phenylethylammonium and BA is butylammonium). Temperature-dependent measurements of free charge-carrier mobilities reveal band transport in these strongly confined semiconductors, with surprisingly high in-plane mobilities. Enhanced charge-phonon coupling is shown to reduce charge-carrier mobilities in (BA)2PbI4 with respect to (PEA)2PbI4. Exciton and free charge-carrier dynamics are disentangled by simultaneous monitoring of transient absorption and THz photoconductivity. A sustained free charge-carrier population is observed, surpassing the Saha equation predictions even at low temperature. These findings provide new insights into the temperature-dependent interplay of exciton and free-carrier populations in 2D MHPs. Furthermore, such sustained free charge-carrier population and high mobilities demonstrate the potential of these semiconductors for applications such as solar cells, transistors, and electrically driven light sources.

Secular equilibrium assessment in a CaWO4 target crystal from the dark matter experiment CRESST using Bayesian likelihood normalisation

Applied Radiation and Isotopes Elsevier 194 (2023) 110670

Authors:

G Angloher, S Banik, G Benato, A Bento, A Bertolini, R Breier, C Bucci, J Burkhart, L Canonica, A D’Addabbo, S Di Lorenzo, L Einfalt, A Erb, FV Feilitzsch, N Ferreiro Iachellini, S Fichtinger, D Fuchs, A Fuss, A Garai, VM Ghete, P Gorla, S Gupta, D Hauff, M Ješkovský, J Jochum, M Kaznacheeva, A Kinast, H Kluck, H Kraus, A Langenkämper, M Mancuso, L Marini, V Mokina, A Nilima, M Olmi, T Ortmann, C Pagliarone, L Pattavina, F Petricca, W Potzel, P Povinec, F Pröbst, F Pucci, F Reindl, J Rothe, K Schäffner, J Schieck, D Schmiedmayer, S Schönert, C Schwertner, M Stahlberg, L Stodolsky, C Strandhagen, R Strauss, I Usherov, F Wagner, M Willers, V Zema, CRESST Collaboration, F Ferella, M Laubenstein, S Nisi

The Low-Energy and Large-Scale Frontier of Dual-Phase Xenon Time Projection Chambers for Dark Matter Search

University of Zurich (2023)

Towards an automated data cleaning with deep learning in CRESST

European Physical Journal Plus Springer 138:1 (2023) 100

Authors:

G Angloher, S Banik, D Bartolot, G Benato, A Bento, A Bertolini, R Breier, C Bucci, J Burkhart, L Canonica, A D’Addabbo, S Di Lorenzo, L Einfalt, A Erb, FV Feilitzsch, N Ferreiro Iachellini, S Fichtinger, D Fuchs, A Fuss, A Garai, VM Ghete, S Gerster, P Gorla, PV Guillaumon, S Gupta, H Kraus

Abstract:

The CRESST experiment employs cryogenic calorimeters for the sensitive measurement of nuclear recoils induced by dark matter particles. The recorded signals need to undergo a careful cleaning process to avoid wrongly reconstructed recoil energies caused by pile-up and read-out artefacts. We frame this process as a time series classification task and propose to automate it with neural networks. With a data set of over one million labeled records from 68 detectors, recorded between 2013 and 2019 by CRESST, we test the capability of four commonly used neural network architectures to learn the data cleaning task. Our best performing model achieves a balanced accuracy of 0.932 on our test set. We show on an exemplary detector that about half of the wrongly predicted events are in fact wrongly labeled events, and a large share of the remaining ones have a context-dependent ground truth. We furthermore evaluate the recall and selectivity of our classifiers with simulated data. The results confirm that the trained classifiers are well suited for the data cleaning task.Comment: 12 pages, 8 figures, 6 table

A next-generation liquid xenon observatory for dark matter and neutrino physics

Journal of Physics G Nuclear and Particle Physics IOP Publishing 50:1 (2022) 13001

Authors:

J Aalbers, Ss AbdusSalam, K Abe, V Aerne, F Agostini, S Ahmed Maouloud, Ds Akerib, Dy Akimov, J Akshat, Ak Al Musalhi, F Alder, Sk Alsum, L Althueser, Cs Amarasinghe, Fd Amaro, A Ames, Tj Anderson, B Andrieu, N Angelides, E Angelino, J Angevaare, Vc Antochi, D Antón Martin, B Antunovic, E Aprile, Hm Araújo, Je Armstrong, F Arneodo, M Arthurs, P Asadi, S Baek, X Bai, D Bajpai, A Baker, J Balajthy, S Balashov, M Balzer, A Bandyopadhyay, J Bang, E Barberio, Jw Bargemann, L Baudis, D Bauer, D Baur, A Baxter, Al Baxter, M Bazyk, K Beattie, J Behrens, Nf Bell

Abstract:

The nature of dark matter and properties of neutrinos are among the most pressing issues in contemporary particle physics. The dual-phase xenon time-projection chamber is the leading technology to cover the available parameter space for weakly interacting massive particles, while featuring extensive sensitivity to many alternative dark matter candidates. These detectors can also study neutrinos through neutrinoless double-beta decay and through a variety of astrophysical sources. A next-generation xenon-based detector will therefore be a true multi-purpose observatory to significantly advance particle physics, nuclear physics, astrophysics, solar physics, and cosmology. This review article presents the science cases for such a detector.