Formation of nucleobases in a Miller-Urey reducing atmosphere.
Proceedings of the National Academy of Sciences of the United States of America 114:17 (2017) 4306-4311
Abstract:
The Miller-Urey experiments pioneered modern research on the molecular origins of life, but their actual relevance in this field was later questioned because the gas mixture used in their research is considered too reducing with respect to the most accepted hypotheses for the conditions on primordial Earth. In particular, the production of only amino acids has been taken as evidence of the limited relevance of the results. Here, we report an experimental work, combined with state-of-the-art computational methods, in which both electric discharge and laser-driven plasma impact simulations were carried out in a reducing atmosphere containing NH3 + CO. We show that RNA nucleobases are synthesized in these experiments, strongly supporting the possibility of the emergence of biologically relevant molecules in a reducing atmosphere. The reconstructed synthetic pathways indicate that small radicals and formamide play a crucial role, in agreement with a number of recent experimental and theoretical results.Spontaneous oxygen isotope exchange between carbon dioxide and natural clays: Refined rate constants referenced to TiO2 (anatase/rutile)
Applied Clay Science Elsevier BV 137 (2017) 6-10
Introduction to the SPARC Reanalysis Intercomparison Project (S-RIP) and overview of the reanalysis systems
Atmospheric Chemistry and Physics Copernicus Publications 17:2 (2017) 1417-1452
Retrieval of ash properties from IASI measurements
ATMOSPHERIC MEASUREMENT TECHNIQUES 9:11 (2016) 5407-5422
Simulation of stratospheric ozone in global forecast model using linear photochemistry parameterization
Asia-Pacific Journal of Atmospheric Sciences Springer Nature 52:5 (2016) 479-494