Oxide electronics

Abstract:

Orbital physics drives a rich phenomenology in transition-metal oxides, providing the microscopic underpinning for effects such as Colossal Magnetoresistance. In particular, magnetic and lattice degrees of freedom are coupled through orbital ordering, and it has long been hoped that this coupling could be exploited to create high-temperature multiferroics with large values of the electrical polarization. Here we report an unprecedented magneto-orbital texture in multiferroic CaMn(7)O(12), found to give rise to the largest magnetically induced ferroelectric polarization measured to date. X-ray diffraction characterization of the structural modulation in these 'magneto-orbital helices', and analysis of magnetic exchange shows that orbital order is crucial in stabilising a chiral magnetic structure, thus allowing for electric polarization. Additionally, the presence of a global structural rotation enables the coupling between this polarization and magnetic helicity required for multiferroicity. These novel principles open up the possibility of discovering new multiferroics with even larger polarization and higher transition temperatures.

Abstract:

This book presents the reader with a fresh and unconventional approach to teaching crystallographic symmetry.

Abstract:

By combining bulk properties, neutron diffraction, and nonresonant x-ray diffraction measurements, we demonstrate that the new multiferroic Cu 3Nb2O8 becomes polar simultaneously with the appearance of generalized helicoidal magnetic ordering. The electrical polarization is oriented perpendicularly to the common plane of rotation of the spins-an observation that cannot be reconciled with the conventional theory developed for cycloidal multiferroics. Our results are consistent with coupling between a macroscopic structural rotation, which is allowed in the paramagnetic group, and magnetically induced structural chirality. © 2011 American Physical Society.