Evidence of rapid hydrogen chloride uptake on water ice in the atmosphere of Mars
Icarus Elsevier 411 (2024) 115960
Abstract:
In 2020, hydrogen chloride (HCl) in the gas phase was discovered in the atmosphere of Mars with the Atmospheric Chemistry Suite (ACS) onboard the Trace Gas Orbiter (TGO) mission (Korablev et al., 2021). Its volume mixing ratio (VMR) shows a seasonal increase of up to 5 ppbv during the perihelion season, followed by a sudden drop to undetectable levels, contradicting modelling estimates of the HCl lifetime of several months. In the Earth's stratosphere, heterogeneous uptake of HCl onto water ice is known to be a major sink for this species. This reaction is now also considered when modelling HCl abundances in the Martian atmosphere. In this work, we use simultaneous measurements of water ice and HCl obtained by the ACS instrument to find particular structures in the vertical profiles as detached gas layers at ice-free altitudes (“ice-holes”). From these particular examples we conclude that the heterogeneous uptake of HCl onto water ice operates on Mars and is a fast mechanism regulating the HCl abundance in the atmosphere of Mars.Modeling Noncondensing Compositional Convection for Applications to Super-Earth and Sub-Neptune Atmospheres
The Astrophysical Journal American Astronomical Society 961:1 (2024) 35-35
Abstract:
Abstract Compositional convection is atmospheric mixing driven by density variations caused by compositional gradients. Previous studies have suggested that compositional gradients of atmospheric trace species within planetary atmospheres can impact convection and the final atmospheric temperature profile. In this work, we employ 3D convection-resolving simulations using Cloud Model 1 (CM1) to gain a fundamental understanding of how compositional variation influences convection and the final atmospheric state of exoplanet atmospheres. We perform 3D initial value problem simulations of noncondensing compositional convection for Earth-air, H 2 , and CO 2 atmospheres. Conventionally, atmospheric convection is assumed to mix the atmosphere to a final, marginally stable state defined by a unique temperature profile. However, when there is compositional variation within an atmosphere, a continuous family of stable end states is possible, differing in the final state composition profile. Our CM1 simulations are used to determine which of the family of possible compositional end states is selected. Leveraging the results from our CM1 simulations, we develop a dry convective adjustment scheme for use in general circulation models (GCMs). This scheme relies on an energy analysis to determine the final adjusted atmospheric state. Our convection scheme produces results that agree with our CM1 simulations and can easily be implemented in GCMs to improve modeling of compositional convection in exoplanet atmospheres.Improved design of an advanced Ice Giants Net Flux Radiometer
Space Science Reviews Springer 220:1 (2024) 5
Abstract:
In this paper, the improved design of an Ice Giants Net Flux Radiometer (IG-NFR), for inclusion as a payload on a future Uranus probe mission, is given. IG-NFR will measure the net radiation flux, in seven spectral bands, each with a 10° Field-Of-View (FOV) and in five viewing angles as a function of altitude. Net flux measurements within spectral filter bands, ranging from solar to far-infrared, will help derive radiative heating and cooling profiles, and will significantly contribute to our understanding of the planet’s atmospheric heat balance and structure, tropospheric 3-D flow, and compositions and opacities of the cloud layers. The IG-NFR uses an array of non-imaging Winston cones integrated to a matched thermopile detector Focal Plane Assembly (FPA), with individual bandpass filters and windows, housed in a vacuum micro-vessel. The FPA thermopile detector signals are read out in parallel mode, amplified and processed by a multi-channel digitizer application specific integrated circuit (MCD ASIC) under field programmable gate array (FPGA) control. The vacuum micro-vessel rotates providing chopping between FOV’s of upward and downward radiation fluxes. This unique design allows for small net flux measurements in the presence of large ambient fluxes and rapidly changing temperatures during the probe descent to ≥10 bar pressure.Detection and Tracking of Space Debris in Cislunar Environment - A Phase 0 Mission Design
Curran Associates (2024) 1188-1204
LIRIS – Lunar Infrared Imaging System for High Resolution Volatile Mapping, a Small Satellite to Support Science and Exploration Missions
Curran Associates (2024) 121-128