Harrison Nicholls (he/him)

Abstract:

Spectroscopic characterization of rocky exoplanets with the James Webb Space Telescope has brought the origin and evolution of their atmospheres into the focus of exoplanet science. Time-evolved models of the feedback between interior and atmosphere are critical to predict and interpret these observations and link them to the solar system terrestrial planets. However, models differ in methodologies and input data, which can lead to significant differences in interpretation. In this paper, we present the experimental protocol of the Coupled atmospHere Interior modeL Intercomparison (CHILI) project. CHILI is an (exo)planet model intercomparison project within the Climates Using Interactive Suites of Intercomparisons Nested for Exoplanet Studies (CUISINES) framework, which aims to support a diverse set of multimodel intercomparison projects in the exoplanet community. The present protocol includes the initial set of participating magma ocean models, divided into evolutionary and static models, and two types of test categories, one focused on solar system planets (Earth and Venus) and the other on exoplanets orbiting low-mass M dwarfs. Both test categories aim to quantify the evolution of key markers of the links between planetary atmospheres and interiors over geological timescales. The proposed tests would allow us to quantify and compare the differences between coupled atmosphere–interior models used by the exoplanet and planetary science communities. Results from the proposed tests will be published in dedicated follow-up papers. To encourage the community to join this comparison effort, and as an example, we present initial test results for the early Earth and TRAPPIST-1 b, conducted with models differing in the treatment of energy transport in the planetary interior and atmosphere, surface boundary layer, geochemistry, and in- and outgassing of volatile compounds.

Abstract:

ABSTRACT While Earth locks much of its carbon in its crust as carbonates, Venus retains a comparable carbon inventory almost entirely in its atmosphere as CO$_2$. On Earth, the geological carbon cycle that has produced this vast crustal carbonate inventory is regulated by biology, liquid water, and plate tectonics, which together have stabilized climate over geological time-scales. Venus presently lacks all these processes. We test whether Venus’s massive CO$_2$ atmosphere is diagnostic of a specific evolutionary pathway by quantifying three routes: primary magma-ocean outgassing, secondary volcanic degassing in a stagnant-lid regime, and remobilization of crustal carbonates after climate destabilization. Using a coupled climate–weathering framework, we find that a past habitable Venus could have stored $\sim$20 bar of CO$_2$ as crustal carbonates. Following the transition to runaway conditions, crustal heating releases this reservoir over tens of Myr. In stagnant-lid secondary-degassing models with a MORB-like mantle, outgassing reaches only $\sim$25 bar CO$_2$, limited by progressive mantle volatile depletion. However, Venus-like inventories can be achieved through: (i) magmatic carbon enrichment, (ii) increased magmatic delivery to the surface (high extrusion or melt production), and (iii) the recycling of undegassed carbon back into the planet’s interior. Primary magma-ocean outgassing can generate $\gt 10^2$ bar CO$_2$, but the retained fraction after early escape remains uncertain. Ultimately, a Venus-like massive CO$_2$ atmosphere is an equifinal outcome and does not uniquely diagnose a temperate past.

Abstract:

Abstract In the aftermath of the Moon-forming giant impact, the Hadean Earth’s mantle and surface crystallized from a global magma ocean blanketed by a dense volatile-rich atmosphere. While prior studies have explored the thermal evolution of such early-Earth scenarios under idealized, oxidizing conditions, the potential feedback between tidal heating driven by Earth–Moon orbital forcing and variable redox scenarios have not yet been explored in detail. We investigate whether tidal heating could have prolonged this early magma ocean phase and supported quasi-steady state epochs of global radiative equilibrium: periods of thermal balance between outgoing radiation and interior heat flux. Using the PROTEUS simulation framework, we simulate Earth’s early evolution under a range of plausible tidal power densities, oxygen fugacities, and volatile inventories. Our results suggest that feedback between tidal heating and atmospheric forcing can induce substantial variation in magma ocean lifetimes, from ∼30 Myr up to ∼500 Myr, sensitive to interior redox conditions. Global radiative equilibrium epochs commonly arise across this range, lasting from ∼2 to ∼320 Myr, and typically occur from 24 Myr after the Moon-forming impact. Under oxidizing conditions, late-stage H 2 O degassing promotes melt retention and sustained heating due to its significant contribution to greenhouse forcing. Weak tides increase the atmospheric abundance of H 2 S and NH 3 and deplete CO. Therefore, the feedback between tides and atmospheric forcing induces a disequilibrium signature in the magma ocean atmosphere.

Abstract:

Abstract Small, low-density exoplanets are sculpted by strong stellar irradiation, but their primordial compositions and subsequent evolution are still unknown. Two often-considered scenarios hold that they formed with rocky interiors and H 2 –He atmospheres (‘gas dwarfs’) or alternatively with bulk compositions dominated by H 2 O phases (‘water worlds’). Here we constrain the possible range of evolutionary histories linking the birth conditions of low-density super-Earth L 98-59 d to recent observations using a coupled atmosphere–interior evolutionary model. We find that the observations can be explained by in situ photochemical production of SO 2 in an H 2 background, indicative of a chemically reducing mantle and substantial (>1.8 mass%) early sulfur and hydrogen content, inconsistent with both the gas-dwarf and water-world scenarios. L 98-59 d’s interior comprises a permanent magma ocean, allowing long-term retention of volatiles within its mantle over billions of years, consistent with California-Kepler Survey trends. Our analysis reveals an evolutionary pathway in which planets host volatile-rich atmospheres sustained by long-term magma-ocean degassing, shaped by secular cooling, atmospheric erosion and photochemistry. Internal and environmental processes contribute to the observed diversity of super-Earth and sub-Neptune exoplanets.