Isotopic ratios in titan's methane: Measurements and modeling

Astrophysical Journal 749:2 (2012)

Authors:

CA Nixon, B Temelso, S Vinatier, NA Teanby, B Bézard, RK Achterberg, KE Mandt, CD Sherrill, PGJ Irwin, DE Jennings, PN Romani, A Coustenis, FM Flasar

Abstract:

The existence of methane in Titan's atmosphere (∼6% level at the surface) presents a unique enigma, as photochemical models predict that the current inventory will be entirely depleted by photochemistry in a timescale of ∼20Myr. In this paper, we examine the clues available from isotopic ratios (12C/13C and D/H) in Titan's methane as to the past atmosphere history of this species. We first analyze recent infrared spectra of CH4 collected by the Cassini Composite Infrared Spectrometer, measuring simultaneously for the first time the abundances of all three detected minor isotopologues: 13CH4, 12CH3D, and 13CH3D. From these we compute estimates of 12C/13C= 86.5 ± 8.2 and D/H= (1.59 ± 0.33) × 10-4, in agreement with recent results from the Huygens GCMS and Cassini INMS instruments. We also use the transition state theory to estimate the fractionation that occurs in carbon and hydrogen during a critical reaction that plays a key role in the chemical depletion of Titan's methane: CH4+ C2H→ CH3+ C2H2. Using these new measurements and predictions we proceed to model the time evolution of 12C/13C and D/H in Titan's methane under several prototypical replenishment scenarios. In our Model1 (no resupply of CH4), we find that the present-day 12C/13C implies that the CH4 entered the atmosphere 60-1600Myr ago if methane is depleted by chemistry and photolysis alone, but much more recently - most likely less than 10Myr ago - if hydrodynamic escape is also occurring. On the other hand, if methane has been continuously supplied at the replenishment rate then the isotopic ratios provide no constraints, and likewise for the case where atmospheric methane is increasing. We conclude by discussing how these findings may be combined with other evidence to constrain the overall history of the atmospheric methane. © 2012 The American Astronomical Society. All rights reserved.

Lunar Net-a proposal in response to an ESA M3 call in 2010 for a medium sized mission

Experimental Astronomy 33:2-3 (2012) 587-644

Authors:

A Smith, IA Crawford, RA Gowen, R Ambrosi, M Anand, B Banerdt, N Bannister, N Bowles, C Braithwaite, P Brown, J Chela-Flores, T Cholinser, P Church, AJ Coates, T Colaprete, G Collins, G Collinson, T Cook, R Elphic, G Fraser, Y Gao, E Gibson, T Glotch, M Grande, A Griffiths, J Grygorczuk, M Gudipati, A Hagermann, J Heldmann, LL Hood, AP Jones, KH Joy, OB Khavroshkin, G Klingelhoefer, M Knapmeyer, G Kramer, D Lawrence, W Marczewski, S McKenna-Lawlor, K Miljkovic, S Narendranath, E Palomba, A Phipps, WT Pike, D Pullan, J Rask, DT Richard, K Seweryn, S Sheridan, M Sims, M Sweeting, T Swindle, D Talboys, L Taylor, N Teanby, V Tong, S Ulamec, R Wawrzaszek, M Wieczorek, L Wilson, I Wright

Abstract:

Emplacement of four or more kinetic penetrators geographically distributed over the lunar surface can enable a broad range of scientific exploration objectives of high priority and provide significant synergy with planned orbital missions. Whilst past landed missions achieved a great deal, they have not included a far-side lander, or investigation of the lunar interior apart from a very small area on the near side. Though the LCROSS mission detected water from a permanently shadowed polar crater, there remains in-situ confirmation, knowledge of concentration levels, and detailed identification of potential organic chemistry of astrobiology interest. The planned investigations will also address issues relating to the origin and evolution of the Earth-Moon system and other Solar System planetary bodies. Manned missions would be enhanced with use of water as a potential in-situ resource; knowledge of potential risks from damaging surface Moonquakes, and exploitation of lunar regolith for radiation shielding. LunarNet is an evolution of the 2007 LunarEX proposal to ESA (European Space Agency) which draws on recent significant advances in mission definition and feasibility. In particular, the successful Pendine full-scale impact trials have proved impact survivability for many of the key technology items, and a penetrator system study has greatly improved the definition of descent systems, detailed penetrator designs, and required resources. LunarNet is hereby proposed as an exciting stand-alone mission, though is also well suited in whole or in-part to contribute to the jigsaw of upcoming lunar missions, including that of a significant element to the ILN (International Lunar Network). © 2011 Springer Science+Business Media B.V.

The 2010 European Venus Explorer (EVE) mission proposal

Experimental Astronomy 33:2-3 (2012) 305-335

Authors:

CF Wilson, E Chassefière, E Hinglais, KH Baines, TS Balint, JJ Berthelier, J Blamont, G Durry, CS Ferencz, RE Grimm, T Imamura, JL Josset, F Leblanc, S Lebonnois, JJ Leitner, SS Limaye, B Marty, E Palomba, SV Pogrebenko, SCR Rafkin, DL Talboys, R Wieler, LV Zasova, C Szopa

Abstract:

The European Venus Explorer (EVE) mission described in this paper was proposed in December 2010 to ESA as an 'M-class' mission under the Cosmic Vision programme. It consists of a single balloon platform floating in the middle of the main convective cloud layer of Venus at an altitude of 55 km, where temperatures and pressures are benign (~25°C and ~0. 5 bar). The balloon float lifetime would be at least 10 Earth days, long enough to guarantee at least one full circumnavigation of the planet. This offers an ideal platform for the two main science goals of the mission: study of the current climate through detailed characterization of cloud-level atmosphere, and investigation of the formation and evolution of Venus, through careful measurement of noble gas isotopic abundances. These investigations would provide key data for comparative planetology of terrestrial planets in our solar system and beyond. © 2011 Springer Science+Business Media B.V.

Further seasonal changes in Uranus' cloud structure observed by Gemini-North and UKIRT

Icarus 218:1 (2012) 47-55

Authors:

PGJ Irwin, NA Teanby, GR Davis, LN Fletcher, GS Orton, SB Calcutt, DS Tice, J Hurley

Abstract:

Near-infrared observations of Uranus were made in October/November 2010 with the Gemini-North telescope in Hawaii, using NIFS, an integral field spectrograph, and the NIRI instrument in imaging mode. Observations were acquired using adaptive optics and have a spatial resolution of approximately 0.1-0.2'.The observed spectra along Uranus' central meridian were analysed using a multiple-scattering retrieval algorithm to infer the vertical/latitudinal variation in cloud optical depth, which we compare with previous observations made by Gemini-North/NIFS in 2009 and UKIRT/UIST observations made between 2006 and 2008. Assuming a continuous distribution of small particles (r~ 1μm, and refractive index of 1.4. +. 0. i) with the single scattering albedo set to 0.75 and using a Henyey-Greenstein phase function with asymmetry parameter set to 0.7 at all wavelengths and latitudes, the retrieved cloud density profiles show that the north polar zone at 45°N has continued to steadily brighten while the south polar zone at 45°S has continued to fade. As with our previous analyses we find that, assuming that the methane vertical profile is the same at all latitudes, the clouds forming these polar zones at 45°N and 45°S lie at slightly lower pressures than the clouds at more equatorial latitudes. However, we also find that the Gemini data can be reproduced by assuming that the main cloud remains fixed at ~2. bar at all latitudes and adjusting the relative humidity of methane instead. In this case we find that the deep cloud is still more opaque at the equator and at the zones at 45°N and 45°S and shows the same seasonal trends as when the methane humidity remain fixed. However, with this approach the relative humidity of methane is seen to rise sharply from approximately 20% at polar latitudes to values closer to 80% for latitudes equatorward of 45°S and 45°N, consistent with the analysis of 2002 HST observations by Karkoschka and Tomasko (Karkoschka, E., Tomasko, M. [2009]. Icarus 202, 287-302), with a possible indication of seasonal variability. Overall, Uranus appeared to be less convectively active in 2010 than in the previous 4. years, supporting the conclusion that now the northern spring equinox (which occurred in 2007) has passed, the atmosphere is settling back into the more quiescent state seen by Voyager 2 in 1986. © 2011 Elsevier Inc.

Models of the global cloud structure on Venus derived from Venus Express observations

Icarus 217:2 (2012) 542-560

Authors:

JK Barstow, CCC Tsang, CF Wilson, PGJ Irwin, FW Taylor, K McGouldrick, P Drossart, G Piccioni, S Tellmann

Abstract:

Spatially-resolved near-infrared spectra from the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on Venus Express have been used to derive improved models of the vertical structure and global distribution of cloud properties in the southern hemisphere of Venus. VIRTIS achieved the first systematic, global mapping of Venus at wavelengths within transparency windows in the 1.6-2.6. μm range, which are sensitive on the nightside to absorption by the lower and middle cloud layers of thermally-emitted radiation from the hot lower atmosphere (Taylor, F.W., Crisp, D., Bézard, B. [1997]. Venus II: Geology, Geophysics, Atmosphere, and Solar Wind Environment, pp. 325-351). The cloud model used to interpret the spectra is based on previous work by Pollack et al. (Pollack, J., Dalton, J., Grinspoon, D., Wattson, R., Freedman, R., Crisp, D., Allen, D., Bézard, B., de Bergh, C., Giver, L. [1993]. Icarus 103, 1-42), Grinspoon et al. (Grinspoon, D.H., Pollack, J.B., Sitton, B.R., Carlson, R.W., Kamp, L.W., Baines, K.H., Encrenaz, T., Taylor, F.W. [1993]. Planet. Space Sci. 41, 515-542) and Crisp (Crisp, D. [1986]. Icarus 67, 484-514), and assumes a composition for the cloud particles of sulfuric acid and water, with acid concentration as a free parameter to be determined. Other retrieved parameters are the average size of the particles and the altitude of the cloud base in the model. Latitudinal variation in the atmospheric temperature structure was incorporated using data from the Venus Radio Science experiment (VeRa). Values are estimated initially using wavelength pairs selected for their unique sensitivity to each parameter, and then validated by comparing measured to calculated spectra over the entire wavelength range, the latter generated using the NEMESIS radiative transfer and retrieval code (Irwin, P.G.J., Teanby, N.A., de Kok, R., Fletcher, L.N., Howett, C.J.A., Tsang, C.C.C., Wilson, C.F., Calcutt, S.B., Nixon, C.A., Parrish, P.D. [2008]. J. Quant. Spectrosc. Radiat. Trans. 109, 1136-1150). The sulfuric acid concentration in the cloud particles is found to be higher in regions of optically thick cloud. The cloud base altitude shows a dependence on latitude, reaching a maximum height near -50°. The increased average particle size near the pole found by Wilson et al. (Wilson, C.F., Guerlet, S., Irwin, P.G.J., Tsang, C.C.C., Taylor, F.W., Carlson, R.W., Drossart, P., Piccioni, G. [2008]. J. Geophys. Res. (Planets) 113, E12) and the finding of spatially variable water vapor abundance at35-40. km altitude first reported by Tsang et al. (Tsang, C.C.C., Wilson, C.F., Barstow, J.K., Irwin, P.G.J., Taylor, F.W., McGouldrick, K., Piccioni, G., Drossart, P., Svedhem, H. [2010]. Geophys. Res. Lett. 37, L02202) are both confirmed. The implications of these improved descriptions of cloud structure and variability for the chemistry, meteorology, and radiative energy balance on Venus are briefly discussed. © 2011 Elsevier Inc.