Reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4)
Chem Commun (Camb) 47 (2011) 7983-7985
Abstract:
We report the reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4, [Zn(Im)(2)]). This occurs irrespective of pore occupancy and takes place via a novel high pressure phase (ZIF-4-I) when solvent molecules are present in the pores. A significant reduction in bulk modulus upon framework evacuation is also observed for both ZIF-4 and ZIF-4-I.The first 21 years of reverse Monte Carlo modelling—a workshop held in Budapest, Hungary (1–3 October 2009)
Journal of Physics Condensed Matter IOP Publishing 22:40 (2010) 400301
The hydrogen-bonding transition and isotope-dependent negative thermal expansion in H3Co(CN)6.
J Phys Condens Matter 22:40 (2010) 404202
Abstract:
We investigate the structures of H(3)Co(CN)(6) and D(3)Co(CN)(6) and their temperature dependence using a combination of advanced neutron and x-ray diffraction techniques. Lattice parameter refinements show marked temperature- and isotope-dependent effects in the thermal expansion behaviour. Reverse Monte Carlo modelling of neutron total scattering data characterizes the distribution of D atom positions in the deuterated compound; analysis of these distributions reveals that the two N-H/D bonds become increasingly different with increasing temperature, suggesting a mechanism for the observed thermal expansion anomalies. We discuss these results in the context of the previous crystallographic, spectroscopic and theoretical results for H(3)Co(CN)(6) and 'super-short' N···H···N systems in general.Risks and causes of musculoskeletal injuries among health care workers
Occupational Medicine Oxford University Press (OUP) 60:5 (2010) 389-394
Metal Ion Roles and the Movement of Hydrogen during Reaction Catalyzed by D-Xylose Isomerase: A Joint X-Ray and Neutron Diffraction Study
Structure Elsevier 18:6 (2010) 688-699