Novel Energy Materials and Advanced Characterisation

Abstract:

The efficiency and longevity of metal-halide perovskite solar cells are typically dictated by nonradiative defect-mediated charge recombination. In this work, we demonstrate a vapor-based amino-silane passivation that reduces photovoltage deficits to around 100 millivolts (>90% of the thermodynamic limit) in perovskite solar cells of bandgaps between 1.6 and 1.8 electron volts, which is crucial for tandem applications. A primary-, secondary-, or tertiary-amino–silane alone negatively or barely affected perovskite crystallinity and charge transport, but amino-silanes that incorporate primary and secondary amines yield up to a 60-fold increase in photoluminescence quantum yield and preserve long-range conduction. Amino-silane–treated devices retained 95% power conversion efficiency for more than 1500 hours under full-spectrum sunlight at 85°C and open-circuit conditions in ambient air with a relative humidity of 50 to 60%.

Abstract:

The description of crystal structures is given starting with some fundamental notions of crystal symmetry. The topics of lattices and space groups are briefly introduced and how these can be used with unit cell contents to describe the crystal structure. This leads to crystallographic databases where information on crystal structures is stored and can be searched. A brief discussion on refinement of diffraction information is given, together with the resulting geometric parameters.

Abstract:

The notion of periodicity in crystals is examined and how this can be varied in practice. In particular, the article discusses first of all the concept of superstructures, in which some sort of alternating motif occurs thus changing the repeat distance in a lattice. Crystals of this type are often incorrectly called in the literature superlattices: first of all they cannot be called lattices at all as they consist of atoms (a lattice must only consist of points). In any case such a superstructure is formed from a sublattice rather than a superlattice. In addition, some crystals do not have normal periodicity within a three-dimensional space, and are known as aperiodic crystals. Despite being aperiodic, they are still ordered. In mathematical terms they can by described with respect to a higher-dimension space and then projected back onto three dimensions. This generalizes our notion of what is meant by a crystal.