Solar system

Abstract:

In this presentation, we will show efforts made to include accurate photochemical modelling of hydrogen chloride (HCl) and ozone (O3) in the Mars Planetary Climate Model in order to reconcile recent observations.The ExoMars Trace Gas Orbiter (TGO) has detected and characterised trace gases in the Martian atmosphere over several Mars years. With its data, upper limits of potential constituents have been constrained, the accuracy of species’ concentration measurements has been improved, and seasonal and spatial variations in the atmosphere have been observed. The wealth of data obtained has addressed several open questions about the nature of Mars’ atmosphere, while other measurements have revealed much that remains poorly understood. For example, models continue to struggle to reproduce ozone distributions, both spatially and temporally, as well as seasonal variations in atmospheric oxygen (O2), suggesting that some key photochemical interactions may be being overlooked. As another example, despite seven years of dedicated observations producing very low upper limits on atmospheric methane levels, there remains no unifying hypothesis that simultaneously explains the detections reported by other Mars assets at Gale Crater [e.g., 1-4].Hydrogen chloride—the first new gas detected by TGO [5,6]—has been investigated recently using the mid-infrared channel on TGO’s Atmospheric Chemistry Suite (ACS MIR) [7,8]. Observations show a strong seasonal dependence of HCl in the atmosphere, with almost all detections occurring during the latter half of the year between the start of dust activity and the southern hemisphere autumnal equinox. There are also unusual measurements of HCl, localised in both time and space, during the aphelion season. Chlorine-bearing species such as HCl are important to understand in the Mars atmosphere because on Earth they are involved in numerous processes throughout the planetary system, including volcanism, from which HCl on Earth ultimately originates. Further, chlorine species play a key role in atmospheric chemistry: they influence oxidative chemistry and variations in the aforementioned O2 and O3 concentrations (e.g., by catalysing the destruction of ozone), and by extension, potential CH4 in the Martian atmosphere [9]. However, much remains unknown about original source and sinks of HCl, as well as the factors controlling its distribution and variation.Here, we use the Mars Planetary Climate Model—a 3-D global climate model that includes a photochemical network—to investigate potential mechanisms accounting for patterns in ozone and HCl detections and interactions between them. We begin with the role of heterogeneous chemistry involving ice and dust aerosols, by implementing modelling developed for the Open University Mars Global Climate Model [10] and building on existing chlorine photochemical model networks [11,12,13]. Heterogeneous chemistry affects the abundances of oxidative species such as OH and HO2, and by extension, O and O3. In addition, we investigate how such processes can potentially serve as a mechanism for direct release and sequestration of HCl from the atmosphere. We also explore potential mechanisms behind the annual occurrence of spatially-constrained aphelion HCl, including volcanic sources, and we investigate the interplay between chlorine-bearing species and OH, HO2,O, and O3. Figure 1 shows the way that HCl appears during spring and summer in the southern hemisphere (solar longitudes 180-360°) when water vapour is present in the Martian atmosphere. Ozone behaves in the opposite manner and is present when water vapour abundances are low. As shown, these species are anti-correlated; we explore the important chemical pathways connecting them.Understanding the role of oxidative chemistry on HCl and other trace gases is key to achieving a more complete picture of processes occurring in the present-day Mars atmosphere, as well as processes that have shaped its evolution and habitability.Figure 1: Observations of CO, O2, O3 and HCl seasonally and across multiple Mars Years. Upper panel: CO and O2 observations from Curiosity’s Sample Analysis at Mars (SAM) instrument (stars; [14]) and the Mars Climate Database (lines; [15]). Lower panel: O3 and HCl observations from TGO’s ACS instrument [8]. MY=Mars Year; NH/SH=northern/southern hemisphere. Figure from Kevin Olsen.References:[1] Giuranna, M., et al. (2019). Nat. Geosci. 12, 326–332. [2] Korablev, O. et al. (2019). Nature 568, 517–520. [3] Montmessin, F. et al. (2021). Astron. Astrophys. 650, A140. [4] Webster, C. R. et al. (2015). Science 347, 415-417. [5] Korablev O. I. et al. (2021). Sci. Adv., 7, eabe4386. [6] Olsen K. S. et al. (2021). Astron. Astrophys., 647, A161. [7] Olsen K. S. et al. (2024a). JGR, 129, e2024JE008350. [8] Olsen K. S. et al. (2024b). JGR, 129, e2024JE008351. [9] Taysum, B. M. et al. (2024). Astron. Astrophys., 687, A191. [10] Brown M. A. J. et al. (2022). JGR, 127, e2022JE007346. [11] Rajendran, K. et al. (2025). JGR: Planets 130(3), p.e2024JE008537. [12] Streeter, P. M. et al. (2025). GRL 52(6), p.e2024GL111059. [13] Benne, B. et al. (2024). EPSC, pEPSC2024-1037. [14] Trainer, M. G. et al. (2019). JGR 124, 3000. [15] Millour, E. et al. (2022). Mars Atmosphere: Modelling and Observations, p. 1103.

Abstract:

In 2018, analysis of Gemini-NIFS near-infrared observations revealed the probable presence of H2S above the main cloud deck on Neptune [1]. The spectral signature of the gas was found to be much stronger at Neptune's south pole compared to regions nearer the equator.Conversely, analysis of Neptune's microwave emission with ALMA suggested strongly enhanced H2S abundances at midlatitudes [2], with much less at the south pole. Determining the true variation of H2S with latitude is crucial for understanding the tropospheric circulation of Neptune.We present our analysis of observations of Neptune from VLT-SINFONI in 2018. Using a limb-darkening approximation, we are able to fit the reflected solar radiance from multiple zenith angles, which allows us to discriminate between gas and aerosol opacity. Despite the lower spectral resolution of this instrument compared to Gemini-NIFS, we are able to detect the H2S spectral signature. With our radiative transfer retrieval code, archNEMESIS [3], we use nested sampling to fit a parameterised cloud model (similar to that of [4]) to these observations over a range of latitudes. We prescribe a latitudinally varying deep methane abundance derived from recent VLT-MUSE observations [5], which enables us to constrain the depth of the cloud top.Our retrieved results are in agreement with the results derived from ALMA [2] - we find a significant enhancement of deep H2S at Neptune's southern midlatitudes, decreasing towards the equator and the pole. Our results show a much deeper cloud top towards the pole, resulting in the increased cloud top column abundance of H2S observed here in the previous near-infrared analysis [1].Figure 1: A comparison of fits to a spectrum extracted from the 50°S to 60°S latitude band, with a model including H2S (blue) and a model without H2S (red). Note the significant discrepancy around 1.58 microns. The models are fitted to spectra at two zenith angles simultaneously.[1] Irwin, P. G., Toledo, D., Garland, R., Teanby, N. A., Fletcher, L. N., Orton, G. S., & Bézard, B. (2019). Probable detection of hydrogen sulphide (H2S) in Neptune’s atmosphere. Icarus, 321, 550-563.[2] Tollefson, J., de Pater, I., Luszcz-Cook, S., & DeBoer, D. (2019). Neptune's latitudinal variations as viewed with ALMA. The Astronomical Journal, 157(6), 251.[3] Alday, J., Penn, J., Irwin, P. G., Mason, J. P., & Yang, J. (2025). archNEMESIS: an open-source Python package for analysis of planetary atmospheric spectra. arXiv preprint arXiv:2501.16452.[4] Irwin, P. G., Teanby, N. A., Fletcher, L. N., Toledo, D., Orton, G. S., Wong, M. H., ... & Dobinson, J. (2022). Hazy blue worlds: a holistic aerosol model for Uranus and Neptune, including dark spots. Journal of Geophysical Research: Planets, 127(6), e2022JE007189.[5] Irwin, P. G., Dobinson, J., James, A., Wong, M. H., Fletcher, L. N., Roman, M. T., ... & de Pater, I. (2023). Latitudinal variations in methane abundance, aerosol opacity and aerosol scattering efficiency in Neptune's atmosphere determined from VLT/MUSE. Journal of Geophysical Research: Planets, 128(11), e2023JE007980.

Abstract:

IntroductionJupiter’s northern Equatorial Zone (EZn) and southern North Equatorial Belt (NEBs) are dominated by three features: five-micron hotspots (seen as North Equatorial Dark Features, NEDFs, in the optical), white cloud plumes, and complex local circulation. These features are influenced by the NEBs jet, which is modulated by a meridionally trapped Rossby wave, in conjunction with the high concentration of ammonia in the EZ and the ammonia depletion in the NEB. Numerous measurements have been made of the temperature, aerosol, and ammonia distributions in this region (c.f. Fletcher et al., 2020). And a number of models have been partially successful at explaining the interrelationships between the observed features (c.f Showman & Dowling, 2000). Here we explore the ammonia and cloud height distribution during 2024-25, when NEDFs and five-micron hotspots were prominent, using the optical band-average technique (Hill et al., 2024, Irwin et al., 2025). We show that while many sensing methods highlight the ammonia and aerosol depletion in five-micron hotspots, this band average method highlights enhancements in ammonia to the south of the hotspots.ObservationsMultiple observations on 2025-01-06 were made allowing coverage of a wide range of longitudes and coverage of a given longitude at several zenith angles. Figure 1 shows maps constructed using the method of Hill et al. (2024). An empirical limb correction is applied in addition to a weighted averaging scheme for overlapping observations. The data clearly show that enhanced ammonia regions lie to the south of NEDFs (labeled 1-4 in order of ascending longitude). For the ammonia enhancements we observe a planetary wave number of nine, within the range of hotspot and NEDF wavenumbers typically observed.DiscussionThe NEBs jet speed peaks at about  7° N, which in fact marks the boundary between the NEDFs and the ammonia enhancements. Anticyclonic gyres are a known feature seen in the same location as we show ammonia enhancements (c.f. Choi et al., 2013). We hypothesize that these gyres are regions of uplift and outflow, bringing up ammonia rich air from deeper levels of the atmosphere. The NEDFs are thought to be areas of subsidence, with cyclonic flow, where dryer air descends from above and results in a clearing of aerosols. Figure 1D shows this schematically with upwelling occurring at the gyres, horizontal winds carrying condensates from the upwelling source to the east and northeast as the visible cloud plumes, and descending clear air in the NEDFs.To further support this hypothesis, we analyze the ammonia mole fraction and cloud pressure at the NEDFs, gyres, and in the plumes through a regions-of-interest (ROI) approach. Figure 2 shows a longitudinal subset of the data in Figure 1, focusing on ammonia regions 3 and 4. Rectangles outline the ROIs which are analyzed for three observation times in Figure 2A. Figure 2B shows a time series of average values at each observation time for cloud pressure and ammonia mole fraction along with statistical errors. Finally, 2C shows scatter plots of the average cloud pressure versus the ammonia abundance. Note the very clear clustering of points where the NEB sample provides a consistent reference with relatively high pressure and very low ammonia abundance. Following the upwelling ammonia, eastward advection of plume aerosols, and NEDF subsidence from Figure 1, we can trace an ammonia cycle between its gaseous source and sink, with an intermediary aerosol state.Future WorkHundreds of observations of NEDFs and ammonia enhancements in the EZn have been made in 2024-25 using the Hill et al. (2024) technique. This data set will be analyzed and assessed for the statistical consistency of the results presented here. In addition, this data set will be compared to complementary multispectral observations to help discriminate why the optical method seems to so clearly detect ammonia enhancements at the 1-2 bar pressure level and why these enhancements appear broad enough to overlap NEDFs.Figure 1. Ammonia mole fraction, cloud pressure, and visual context maps created from observations on 2025-01-06 using an 11 inch Schmidt-Cassegrain telescope. A) Ammonia mole fraction (ppm) with enhanced areas labeled 1-4 in order of ascending longitude. The black circle at left shows the approximate spatial resolution of the data. B) Cloud pressure (mbar). C) Visual context image with selected contour overlays to show enhanced ammonia mole fraction and lowest pressure (highest) clouds. D) Same as C), but with arrows indicating presumed upwelling (black ⊙), downwelling (white ⦻), and horizontal flow (red arrows). Figure 2. Two ammonia enhancements (4 & 3 from Figure 1), associated plumes, and NEDFs are analyzed for cloud pressure and ammonia abundance. Three observations are assessed with the targets near nadir viewing. A) Ammonia mole fraction, cloud pressure, and visual context image with overlaid rectangles indicating regions-of-interest (ROIs). B) Time series of cloud pressure (left) and ammonia mole fraction (right) over the three observations. C) Scatter plot of all ammonia and cloud measurements in each ROI (left) and of the averages over the three observations. Note that the NEB data are provided as a stable reference.ReferencesChoi, D. S. et al. 2013. Icarus, 223, 832. Hill, S. M. et al. 2024. Earth and Space Science, 11(8), e2024EA003562.Fletcher, L. N. et al. 2020. Journal of Geophysical Research (Planets), 125, e06399. Irwin, P. G. J. et al. 2025. Journal of Geophysical Research: Planets, 130(1), e2024JE008622. Showman, A. P., & Dowling, T. E. 2000. Science, 289, 1737-1740. 

Abstract:

Survive or not survive, that is the question of the 500-hour JWST Rocky Worlds DDT Program. Whether a terrestrial planets’ atmosphere can suffer under the intense XUV of its host, or if it completely escapes, these are the questions we explore. Zahnle & Catling (2017) defined the Cosmic Shoreline, but recent observations from JWST reveal airless worlds around M-stars, calling for a refinement of this “receding” shoreline (Pass et al. 2025). M-stars spend a longer time in pre-main sequence, subjecting their orbiting worlds to some higher intensity XUV activity. This complicates our present understanding of this shoreline. Investigating chemical effects of planet-star interactions could be the key to a more complete picture of this shoreline.  We investigate the interplay between photochemistry, mixing, and escape of carbon dioxide atmospheres under intense and mild XUV fluxes as follow on work to both Johnstone et al. (2018) and Nakayama et al. (2022). We expand on this work by adopting thermal structure models from Nakayama et al. (2022) and apply them to identify key chemical pathways for escape. We create a reduced C-O chemical network including neutral and ionic species to identify these pathways. As photochemistry simulations take into account many reactions, these 1D calculations are too computationally expensive to be done in 3D. Although rudimentary at best, the mixing parameter– eddy diffusion term, K_zz, comprises the dynamical element of 1D photochemical simulations. Here, we consider the mixing of photochemical products in competition with escape to explore the chemical pathways of retention and loss. We compare the photochemical model results for active and inactive cases for the Trappist-1 system planets. Then, using the resulting composition-dependent heating and cooling rates for Trappist-1 planets, we assess their propensity for efficient atomic line cooling versus escape. We follow the work of Chatterjee & Pierrehumbert (2024) in this assessment.  Finally, using our pathway analysis, we find an analytical formula for calculating an energy-limited escape boundary for these planets based on composition.  It is important here to note the limitations of 1D work. First, there exists an exchange of rigor between modelling chemistry and dynamics. Insights from this work are ripe for implementation into 3D GCMs, especially in response to incorporating UV-driven processes for thermospheric modelling mentioned in Ding and Wordsworth (2019). Second, interaction with the interior is important in the early phase of planetary formation, i.e., the magma ocean phase. Due to exchange between atmosphere and magma early in the planet’s formation, incorporation with an interior-atmosphere model would better constrain higher pressure chemical abundances. Although this work focuses on the upper atmosphere, extrapolation to the surface environment is a key goal for understanding a planet.  Considering planet-star interaction is imperative for the selection of targets for observation. However, it is also important when considering anomalous detections of atmospheres around planets predicted to not have an atmosphere. This could be a first step in determining an atmosphere as non-primary and/or distinguishing between an airless planet and one with high altitude haze.

Abstract:

NASA’s Lucy mission [1] successfully completed a flyby encounter with the main-belt asteroid (52246) Donaldjohanson on April 20, 2025, collecting data as part of a full-scale operational test for Lucy’s future Trojan encounters.  Donaldjohanson was known to be a C-type asteroid and based on our ground-based observations, to have a Fe-bearing phyllosilicate 0.7 µm absorption. Similar absorptions in spectra of CI, CM, and CR carbonaceous chondrites are indicative of aqueously altered mafic silicates [2-4]. Donaldjohanson is also a member of the 155 Mya Erigone family [5], which is dominated by objects that have also been inferred to be aqueously altered based on their visible 0.7 µm absorptions [6].The Multi-spectral Visible Imaging Camera (MVIC), part of Lucy’s L’Ralph instrument [7-8], was specifically designed to include a filter covering the 0.7 µm absorption to detect evidence of aqueous alteration on the mission’s primary Trojan targets. The Donaldjohanson encounter is thus an excellent opportunity to compare the performance and calibration of MVIC to ground-based data. Here, we will report on both these validation efforts and our exploration of the spatial variability of the 0.7 µm phyllosilicate absorption across the imaged surface of Donaldjohanson to understand potential variability with surface features and photometry, and in relation to other Erigone family objects.References: [1] Levison et al. (2021) PSJ. [2] Cloutis et al. (2011a) Icarus. [3] Cloutis et al. (2011b) Icarus. [4] Cloutis et al. (2012) Icarus. [5] Marchi et al., (2025) PSJ. [6] Morate, D., et al. (2016) A&A. [5] Reuter et al. (2023), SSR. [6] Simon, A.A., et al. 2025 PSJ.Acknowledgments: The Lucy mission is funded through the NASA Discovery Program (Contract No. NNM16AA08C).