Dr. Claire Marie Guimond

Volcanic gases supplied a large part of Earth's early atmosphere, but constraints on the value of this flux are scarce. Here we model how C-O-H outgassing could have evolved through the late Hadean and early Archean, under the conditions that global plate tectonics had not yet initiated, all outgassing was subaerial, and graphite was the stable carbon phase in the melt source regions. The model fully couples numerical mantle convection, partitioning of volatiles into the melt, and chemical speciation in the gas phase. The mantle oxidation state (which may not have reached late Archean values in the Hadean) is the dominant control on individual species' outgassing rates because it affects both the carbon content of basaltic magmas and the speciation of degassed volatiles. Volcanic gas from mantles more reduced than the iron-wüstite mineral redox buffer would contain virtually no CO2 because (i) carbonate ions dissolve in magmas only in very limited amounts, and (ii) almost all degassed carbon takes the form of CO instead of CO2. For oxidised mantles near the quartz-fayalite-magnetite buffer, we predict median CO2 outgassing rates of less than approximately 5 Tmol yr−1, still lower than the outgassing rates used in many Archean climate studies. Relatively weak outgassing is due in part to the redox-limited CO2 contents of graphite-saturated melts, and also to a stagnant lid regime's inefficient replenishment of upper mantle volatiles. Our results point to certain chemical and geodynamic prerequisites for sustaining a clement climate with a volcanic greenhouse under the Faint Young Sun.

Volcanic degassing of planetary interiors has important implications for their corresponding atmospheres. The oxidation state of rocky interiors affects the volatile partitioning during mantle melting and subsequent volatile speciation near the surface. Here we show that the mantle redox state is central to the chemical composition of atmospheres while factors such as planetary mass, thermal state, and age mainly affect the degassing rate. We further demonstrate that mantle oxygen fugacity has an effect on atmospheric thickness and that volcanic degassing is most efficient for planets between 2 and 4 Earth masses. We show that outgassing of reduced systems is dominated by strongly reduced gases such as H2, with only smaller fractions of moderately reduced/oxidised gases (CO, H2O). Overall, a reducing scenario leads to a lower atmospheric pressure at the surface and to a larger atmospheric thickness compared to an oxidised system. Atmosphere predictions based on interior redox scenarios can be compared to observations of atmospheres of rocky exoplanets, potentially broadening our knowledge on the diversity of exoplanetary redox states.

Direct imaging is likely the best way to characterize the atmospheres of Earth-sized exoplanets in the habitable zone of Sun-like stars. Previously, Stark et al. (2014, 2015, 2016) estimated the Earth twin yield of future direct imaging missions, such as LUVOIR and HabEx. We extend this analysis to other types of planets, which will act as false positives for Earth twins. We define an Earth twin as any exoplanet within half an e-folding of 1 AU in semi-major axis and 1 R⊕ in planetary radius, orbiting a G-dwarf. Using Monte Carlo analyses, we quantify the biases and planetary false positive rates of Earth searches. That is, given a pale dot at the correct projected separation and brightness to be a candidate Earth, what are the odds that it is, in fact, an Earth twin? Our notional telescope has a diameter of 10 m, an inner working angle of 3{\lambda}/D, and an outer working angle of 10{\lambda}/D (62 mas and 206 mas at 1.0 {\mu}m). With no precursor knowledge and one visit per star, 77% of detected candidate Earths are actually un-Earths; their mean radius is 2.3 R⊕, a sub-Neptune. The odds improve if we image every planet at its optimal orbital phase, either by relying on precursor knowledge, or by performing multi-epoch direct imaging. In such a targeted search, 47% of detected Earth twin candidates are false positives, and they have a mean radius of 1.7 R⊕. The false positive rate is insensitive to stellar spectral type and the assumption of circular orbits.