Laboratory measurements of the optical properties of sea salt aerosol
Atmospheric Chemistry and Physics 9:1 (2009) 221-230
Abstract:
The extinction spectra of laboratory generated sea salt aerosols have been measured from 1μm to 20μm using a Bruker 66v/S FTIR spectrometer. Concomitant measurements include temperature, pressure, relative humidity and the aerosol size distribution. The refractive indices of the sea salt aerosol have been determined using a simple harmonic oscillator band model (Thomas et al., 2004) for aerosol with relative humidities at eight different values between 0.4% to 86%. The resulting refractive index spectra show significant discrepancies when compared to existing sea salt refractive indices calculated using volume mixing rules (Shettle and Fenn, 1979). Specifically, an additional band is found in the refractive indices of dry sea salt aerosol and the new data shows increased values of refractive index at almost all wavelengths. This implies that the volume mixing rules, currently used to calculate the refractive indices of wet sea salt aerosols, are inadequate. Furthermore, the existing data for the real and imaginary parts of the refractive indices of dry sea salt aerosol are found not to display the Kramers-Kronig relationship. This implies that the original data used for the volume mixing calculations is also inaccurate.Laboratory measurements of the optical properties of sea salt aerosol
Atmospheric Chemistry and Physics Discussions 8:1 (2008) 71-94
HIRDLS Instrument Radiometric Calibration Black Body Targets
Proceedings of SPIE the International Society for Optical Engineering 5152 (2003) 223-230
Abstract:
The pre-launch calibration of the HIRDLS instrument took place in a dedicated facility at the University of Oxford. One aspect of this calibration was the determination of the response of the instrument to black body radiation. This was achieved with the use of purpose built full aperture black body targets which were mounted in the vacuum chamber together with all of the calibration equipment. Especial attention was placed on the absolute knowledge of the emission from these targets. This was done through a combination of thermometric sensor calibration traceable to the International Temperature Standard (ITS-90), surface emission measurements, cavity design and modelling and controlling the stray light sources in the vacuum chamber. This paper describes the design requirements, implementation and performance achieved.Mirror emissivity measurements for the NASA AURA HLRDLS instrument
Proceedings of SPIE the International Society for Optical Engineering 5152 (2003) 238-246
Abstract:
The High Resolution Dynamics Limb Sounder (HIRDLS) instrument is scheduled for launch on the NASA AURA satellite in January 2004; it is a joint project between the UK and USA. HIRDLS is a mid-infrared limb emission sounder which will measure the concentrations of trace species and aerosol, and temperature and pressure variations in the Earth's atmosphere between about 8 and 100 km altitude on a finer spatial scale than been achieved before. HIRDLS has particularly stringent radiometric calibration accuracy requirements. A warm (280-300K) 'In-Flight Calibrator' (IFC) black cavity within the instrument plus a view to cold space are used to perform radiometric calibration. The cavity has an entrance aperture which is much smaller than the full beam size, and it is viewed through a focusing mirror. The cavity and focusing mirror are ideally maintained at the same temperature but differences of up to 1 C may exist, in which case a correction utilising the mirror emissivity can usefully be made. That emissivity has been measured at instrument level during pre-launch calibration by viewing an external target at the same temperature as the IFC while varying the calibration mirror temperature.Pre-laimch calibration of the NASA AURA HIRDLS instrument
Proceedings of SPIE the International Society for Optical Engineering 5152 (2003) 172-180