Professor Roy Grainger

Abstract:

Operationally only pressure, temperature and six significant trace gases are retrieved by ESA from MIPAS data. However, information on many other species is also present in the spectra. We apply a variety of techniques and our own retrieval model to retrieve the concentration of three other species: SO 2,OCS and SF6. Sulphur Dioxide (SO2) is an acidic gas with both natural and anthropogenic sources that is rapidly converted to sulphuric acid and hence sulphate aerosols in the atmosphere. Carbonyl Sulphide (OCS) is produced naturally at the ocean surface and by biomass burning and, through stratospheric oxidation, it is thought to be the main contributor to non-volcanic stratospheric sulphate aerosols. Sulphur Hexafluoride (SF 6) is almost entirely anthropogenic in its origins and shows steady year-on-year increases making it useful for age of air and tracer studies. We anticipate the good global coverage and continuity of data will make MIPAS useful for the determination of changes and trends in the quantity and distribution of these species both natural and anthropogenic. In this paper we summarise the current progress that has been made in the retrieval of these important sulphur-containing species. We show some preliminary zonal mean fields and briefly outline the methods applied.

Abstract:

Observations from the International Satellite Cloud Climatalogy Project (ISCCP) are used to demonstrate that the 19-level HadAM3 version of the United Kingdom Met Office Unified Model does not simulate sufficient high cloud over land. By using low-altitude winds, from the European Centre for Medium Range Weather Forecasting (ECMWF) Re-Analysis from 1979 to 1994 (ERA-15) to predict the areas of maximum likelihood of orographic wave generation, it is shown that much of the deficiency is likely to be due to the lack of a representation of the orographic cirrus generated by sub-grid scale orography. It is probable that this is a problem in most GCMs.

Abstract:

A new method for the retrieval of the spectral refractive indices of micrometer-sized particles from infrared aerosol extinction spectra has been developed. With this method we use a classical damped harmonic-oscillator model of molecular absorption in conjunction with Mie scattering to model extinction spectra, which we then fit to the measurements using a numerical optimal estimation algorithm. The main advantage of this method over the more traditional Kramers-Kronig approach is that it allows the full complex refractive-index spectra, along with the parameters of the particle size distribution, to be retrieved from a single extinction spectrum. The retrieval scheme has been extensively characterized and has been found to provide refractive indices with a maximum uncertainty of similar to10% (with a minimum of similar to0.1%). Comparison of refractive indices calculated from measurements of a ternary solution of HNO3, H2SO4, and H2O with those published in J. Phys. Chem. A 104, 783 (2000) show similar differences as found by other authors. (C) 2005 Optical Society of America.