Dr. Katherine Shirley (she/her)

Abstract:

Laboratory spectral analysis of well-characterized meteorite samples can be employed to more quantitatively analyze asteroid remote sensing data in conjunction with returned extraterrestrial samples. In this work, we examine the combined effects of physical (temperature, particle size) and chemical (petrologic type, metal fraction) variables on visible and near-infrared (VNIR) spectra of ordinary chondrite meteorite powders. Six equilibrated ordinary chondrite meteorite falls were prepared at a variety of particle sizes to capture the spectral diversity associated with asteroid regoliths dominated by various grain sizes. Mineral compositions and abundance were determined from electron microprobe analysis of meteorite thick sections to precisely characterize changes in spectral features due to variations in mineralogy. VNIR spectra of the ordinary chondrites were measured under simulated asteroid surface conditions at a series of temperatures chosen to mimic near-Earth asteroid surfaces. The resulting spectra show minimal variation in both major absorption bands across the simulated near-Earth asteroid temperature regime. Changes in particle size result in variations in band centers and band area ratios for material of the same composition, two key parameters typically used to derive asteroid composition. Unlike previous spectral investigations of ordinary chondrites, we retained the metal fraction in our powders instead of analyzing only the silicate fraction. Metal has a subtle but non-negligible effect on the VNIR spectra of ordinary chondrites. The more petrologically pristine samples from each ordinary chondrite group display relatively weaker absorption bands than their more thermally altered counterparts. The band centers shift to longer wavelengths as grain size and petrologic type increase.

Abstract:

The Lunar Trailblazer smallsat mission High-resolution Volatiles and Minerals Moon Mapper (HVM³) science instrument was designed to acquire targeted spectral image cubes of the lunar surface at visible to shortwave infrared (VSWIR) wavelengths (0.6–3.6 μm) in an effort to understand the distribution, abundance, and form (OH, H2O, ice) of lunar water, as well as the lunar water cycle. The Lunar Trailblazer mission end was declared in July 2025. Here, we describe the formulation and testing of VSWIR spectral parameters in preparation for previously anticipated returned data from HVM³ using global image cubes and mosaic data from the Moon Mineralogy Mapper (M³) imaging spectrometer, HVM³'s predecessor, and the Deep Impact spacecraft. We expand upon the existing M³ global spectral parameter library, test the efficacy of presented parameters individually and alongside existing M³ spectral parameters, provide examples of quantitative thresholds intended to indicate robust mineral detections, and discuss the spectral parameter limitations. We demonstrate that newly formulated and existing parameters capture lunar mineral diversity well and serve as a reliable indicator of lunar surface hydration, making them useful for existing and future scientific analysis using lunar orbital remote sensing data sets.

Abstract:

Research into compositions of small bodies and planetary surfaces, such as asteroids, is key to understanding the origin of water and organics on Earth [1], as well as placing constraints on planetary dynamics and migration models [2] that can help understand how planetary systems around other stars may form and evolve. Compositional estimates can be found with thermal infrared (TIR; 5-25μm) spectroscopy, as the TIR region is rich in diagnostic information and can be used in remote sensing observations and laboratory measurements. However, TIR spectra of the same material may appear differently depending on several factors, such as particle size, surface roughness, porosity etc. This work quantifies the changes in spectral morphology (i.e., shapes and depths of spectral features) as particle size transitions from fine (90%), at several size fractions, aimed to be

Abstract:

Introduction: The origins of Mars' moons, Phobos and Deimos, remain uncertain, with two main hypotheses under consideration: formation from debris following a high-energy impact between Mars and an asteroid [1], or capture of primitive asteroids [2]. To address this, JAXA's Martian Moons eXploration (MMX) mission aims to return samples from Phobos by 2031 [3]. The characterisation of these samples will determine the origin of Phobos.To ground-truth remote observations of Phobos, we have used X-ray diffraction (XRD), and Fourier transform infrared (FTIR) reflectance spectroscopy to characterise the bulk mineralogy and IR spectral properties of ureilites, carbonaceous and ordinary chondrites, the composition of which could be indicative of a captured asteroid [4], and Martian meteorites that could represent a collisional formation. By acquiring XRD and IR data from the same material, mineral abundances can be directly correlated with features in reflectance spectra [5]. When MMX reaches Phobos, meteorite data collected in the laboratory will play a crucial role towards interpreting the mineralogy and composition of materials on its surface.Methods: We have characterised the mineralogy and spectral properties of six CM (Mighei-like) carbonaceous chondrites, Tarda (C2-ung), the CO (Ornans-like) chondrite Kainsaz, a range of shock darkened ordinary chondrites (mostly falls) including L4-6, and H5-6, four CR2 chondrites, four ureilites, Martian meteorites Nakhla and Tissint, and a Tagish Lake (C2-ung) based simulant created by the University of Tokyo, known as UTPS-TB [6]. For the meteorites, chips of approximately 200 mg were ground to produce powders with grain sizes of less than 40 microns. The UTPS-TB sample came in a powdered form which was ground to the same grain size as the meteorites.Diffuse reflectance spectra (1.7 - 50 μm) were collected using a Bruker VERTEX 70V FTIR spectrometer at the University of Oxford Planetary Spectroscopy Facility. Spectra were calibrated at the start of each measurement day and between measurements of samples using a gold standard. The powdered sample was measured under a vacuum to reduce terrestrial atmospheric contributions.XRD patterns of the same powders were collected using an INEL X-ray diffractometer with a position-sensitive detector at the Natural History Museum, London. Around 50 mg of powdered sample was measured for 16 hours to achieve good signal-to-noise. Measurements of well-characterised standard minerals were collected for 30 minutes and compared with meteorite patterns to identify minerals and quantify their abundance in the sample [e.g. 7].Results & Discussion: The mineralogical and spectral characteristics of meteorites in this investigation are compared the reflectance spectra of Phobos’ surface. The CR chondrites are primitive, containing both anhydrous silicates (e.g. olivine and pyroxene) and aqueous alteration phases such as phyllosilicates, carbonates, magnetite, and sulfides. Their albedo is ~3-5% reflectance with a weak red slope in the visible to near-infrared (VNIR). The CRs have a 3 μm hydration band, due to partial aqueous alteration. Their low VNIR reflectance, red-sloped continuum, and weak 3 μm spectral absorption feature is like that of Phobos, supporting the captured asteroid origin theory. The CM chondrites share similar spectral features but have a lower albedo and a stronger μm hydration band, corresponding to a higher phyllosilicate composition.   The ureilites are achondritic ultramafic meteorites containing olivine, pyroxene and carbon phases. These samples have a low albedo (~6-15% in VNIR) due to their opaque carbonaceous composition. However, their VNIR spectra are blue-sloped, inconsistent with Phobos’ red-sloped spectra. Ureilites are also anhydrous and therefore lack the 3 μm hydration band seen in Phobos spectra. Their low reflectance and feature-poor spectra could resemble Phobos, however there is a significant difference in spectral slope and hydration features. Therefore, Phobos were composed of ureilitic material, its surface would need to be significantly modified by space weathering.Martian meteorites Nakhla (a nakhlite) and Tissint (a shergottite) have mineralogical and spectral features consistent with their basaltic origin. XRD measurements of these meteorites are dominated by pyroxene (augite, pigeonite), and olivine, consistent with their origin in the Martian crust. Their reflectance spectra have relatively high albedo, mafic absorption bands at ~1 and 2 μm, and a lack of hydration features. These features are inconsistent with the spectra of Phobos, which lack 1 or 2 μm bands and show significantly lower reflectance.CR and CM chondrites are the closest spectral match to Phobos from the samples studied. Their low albedo, red-sloped, hydrated spectra are consistent with surface measurements of Phobos. Ureilites share low reflectance but differ significantly in slope and hydration, while Martian meteorites differ in more spectral characteristics. These results support the interpretation that Phobos is composed of primitive, carbon-rich material, likely of outer solar system origin, and favour a capture scenario over a collisional formation from Martian ejecta. The similarities between the carbonaceous chondrites and Phobos indicates that the Martian moons may be captured asteroids and further demonstrates the importance of the MMX mission sample return for solving the mystery of their origin definitively.References: [1] R. Citron et al. (2015) Icarus 252:334-338. [2] M. Pajola et al. (2013) The Astrophysical Journal 777:127. [3] K. Kuramoto et al. (2022) Earth, Planets and Space 74:12. [4] K. D. Pang et al. (1978) Science 199(4324):64-66. [5] H. C. Bates et al. (2023) Meteoritics & Planetary Science 1-23. [6] H. Miyamoto et al. (2021) Earth, Planets and Space 73:1-17 [7] G. Cressey et al. (1996) Powder Diffraction 11:35-39.