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CMP
Credit: Jack Hobhouse

Prof Henry Snaith FRS

Professor of Physics

Sub department

  • Condensed Matter Physics

Research groups

  • Snaith group
  • Advanced Device Concepts for Next-Generation Photovoltaics
Henry.Snaith@physics.ox.ac.uk
Robert Hooke Building, room G21
  • About
  • Publications

Revealing the nature of photoluminescence emission in the metal-halide double perovskite Cs2AgBiBr6

Journal of Materials Chemistry C Royal Society of Chemistry 7:27 (2019) 8350-8356

Authors:

SJ Zelewski, JM Urban, A Surrente, DK Maude, A Kuc, Laura Schade, Roger Johnson, Markus Dollmann, Pabitra Nayak, Henry Snaith, Paolo Radaelli, R Kudrawiec, Robin Nicholas, P Plochocka, M Baranowski

Abstract:

Double perovskite crystals such as Cs2AgBiBr6 are expected to overcome the limitation of classic hybrid organic–inorganic perovskite crystals related to the presence of lead and the lack of structural stability. Perovskites are ionic crystals in which the carriers are expected to strongly couple to lattice vibrations. In this work we demonstrate that the photoluminescence (PL) emission in Cs2AgBiBr6 is strongly influenced by the strong electron–phonon coupling. Combining photoluminescence excitation (PLE) and Raman spectroscopy we show that the PL emission is related to a color center rather than a band-to-band transition. The broadening and the Stokes shift of the PL emission from Cs2AgBiBr6 is well explained using a Franck–Condon model with a Huang–Rhys factor of S = 11.7 indicating a strong electron–phonon interaction in this material.

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Azetidinium as Cation in Lead Mixed Halide Perovskite Nanocrystals of Optoelectronic Quality

(2019)

Authors:

Sameer Vajjala Kesava, Yasser Hassan, Alberto Privitera, Aakash Varambhia, Henry J Snaith, Moritz K Riede
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Low cost triazatruxene hole transporting material for >20% efficiency perovskite solar cells

Journal of Materials Chemistry C Royal Society of Chemistry (RSC) 7:18 (2019) 5235-5243

Authors:

Arthur Connell, Zhiping Wang, Yen-Hung Lin, Peter C Greenwood, Alan A Wiles, Eurig W Jones, Leo Furnell, Rosie Anthony, Christopher P Kershaw, Graeme Cooke, Henry J Snaith, Peter J Holliman
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Long-Range Charge Extraction in Back-Contact Perovskite Architectures via Suppressed Recombination

Joule Elsevier 3:5 (2019) 1301-1313

Authors:

Gregory D Tainter, Maximilian T Hörantner, Luis M Pazos-Outón, Robin D Lamboll, Haralds Āboliņš, Tomas Leijtens, Suhas Mahesh, Richard H Friend, Henry J Snaith, Hannah J Joyce, Felix Deschler
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Fractional Deviations in Precursor Stoichiometry Dictate the Properties, Performance and Stability of Perovskite Photovoltaic Devices

(2019)

Authors:

Paul Fassl, Vincent Lami, Alexandra Bausch, Zhiping Wang, Matthew T Klug, Henry J Snaith, Yana Vaynzof
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