X-ray and neutron scattering

Abstract:

We present the magnetic phase diagram of multiferroic TbMnO3 for H parallel to b determined using X-ray resonant scattering at the Tb L-3-edge. Investigations of two different magnetic domains, C-type and F-type, demonstrate very similar behaviour in high applied magnetic fields, with a low temperature incommensurate to commensurate transition at H similar or equal to 4.5T, concurrent with the polarisation flop observed in bulk magnetoelectric measurements. (C) 2009 Elsevier B.V. All rights reserved.

Abstract:

The crystal structure of Na0.75CoO2 was studied at ambient and low temperatures down to 10 K at pressures up to 40 GPa using synchrotron x-rays and a diamond cell in angle dispersion geometry. A reduction in the c / a ratio was observed at both conditions with the application of pressure. An increase in Co-O bond lengths and a decrease in Na-O bond lengths were observed above 10 GPa. The results of the density functional calculations performed agree well with the pressure induced bond length changes. The anomalous change in the c / a ratio and bond lengths indicate a pressure induced isostructural phase transition above 10 GPa. Bulk modulus calculations show this compound is less compressible than its hydrated analogues. © 2009 Elsevier Ltd.

Abstract:

Polarized- and unpolarized-neutron scattering measurements of the spin excitation spectrum in the stripe-ordered phase of La(2)NiO4+delta(delta similar or equal to 0.11) are presented. At low energies, the magnetic spectral weight is found to shift anomalously toward the two-dimensional antiferromagnetic wave vector, similar to the low-energy dispersions observed in cuprate superconductors. While spin-wave spectra in stripe phases can exhibit an apparent inward dispersion, we find that the peak shifts measured here cannot be accounted for by this effect. Possible extensions of the model are discussed.