Planetary atmosphere observation analysis

Abstract:

Remote spectroscopy is used to characterize the mineralogy and infer the history of planetary bodies. Carbonaceous asteroids, such as B‐type (101955) Bennu, represent the earliest stages of planet formation. B types have a blue (negative) spectral slope and comprise <5% of asteroids. Samples from Bennu returned by the OSIRIS‐REx spacecraft complement remote observations of this rare population. We show here, using laboratory spectra that are directly comparable to spacecraft data, that OSIRIS‐REx accurately determined Bennu's dust content and most of its surface composition. However, spectra of the asteroid exhibit stronger water absorptions than those of bulk samples, possibly due to hydrous, Mg‐rich phosphate or solar wind implantation at Bennu's uppermost surface. Bennu samples spectrally resemble the most aqueously altered carbonaceous meteorites and samples of (162173) Ryugu, indicating similarly pervasive aqueous alteration. However, one carbon‐enriched Bennu stone does not appear to have a spectral analog among Ryugu samples or meteorites. Our findings demonstrate the leverage obtained using a wide range of wavelengths and that sample analysis anchors the interpretations of remote sensing, leading to more robust characterization of planetary surface composition and evolution.

Abstract:

The origin of the red colouration in Jupiter's Great Red Spot (GRS) is a long-standing question in planetary science. While several candidate chromophores have been proposed, no clear conclusions have been reached regarding its nature, evolution, or relationship to atmospheric dynamics. In this work, we perform microphysical simulations of the reddish haze over the GRS and quantify the production rates and timescales required to sustain it. Matching the previously reported chromophore column mass and effective radius in the GRS requires column-integrated injection fluxes in the range 1×10⁻¹²–7×10⁻¹² kg m⁻² s⁻¹, under low upwelling velocities in the upper troposphere (v<inf>trop</inf>≲1.5×10⁻⁴ m s⁻¹) and particle charges of at least 20 electrons/μm. Such rates exceed the mass flux that standard photochemical models of Jupiter currently supply via NH<inf>3</inf>–C<inf>2</inf>H<inf>2</inf> photochemistry at 0.1–0.2 bar, the most popular chromophore pathway in recent literature. We find a lower limit of 7 years on the haze formation time. We also assess commonly used size and vertical distribution parameterisations for the chromophore haze, finding that eddy diffusion prevents the long-term confinement of a thin layer and that the extinction is dominated by particles that can be represented by a single log-normal size distribution.

Abstract:

We report the first detection of stratospheric propadiene (CH₂CCH₂) and propene (C₃H₆) at Jupiter’s mid-to-high northern latitudes using IRTF-TEXES measurements recorded on March 5-6, 2025. Using radiative transfer software to quantitatively test for the presence of propadiene and propene, we report a >12-σ detection of propadiene and a >17-σ detection of propene at high latitudes inside Jupiter’s auroral region, where the species are most concentrated. For example, at 62 °N (planetocentric) inside Jupiter’s northern auroral region (henceforth ‘NAR’), we derive a 1-mbar propadiene abundance of 2.0 ± 0.2 ppbv, which is 40 ± 3 higher than abundances predicted by the Moses and Poppe (2017) photochemical model (henceforth ‘MP17’), and significantly higher than the 1.2-pbbv upper limit abundance derived at 42 °N (the lowest latitude sampled by the observations). Similarly, we derive a 1-mbar propene abundance 8.1 ± 0.5 ppbv at 62 °N inside Jupiter’s NAR, which is 28 ± 2 higher than the MP17 predicted abundance and significantly higher than the 6-ppbv 1-mbar upper limit abundance derived at 42 °N. The fact that propadiene and propene are most enriched inside Jupiter’s NAR strongly suggests that perturbations to the chemistry by auroral-related heating and exogenous ions/electrons are responsible for their significant enrichment, as has been observed for other unsaturated/aromatic hydrocarbon species. Spectral features of propane (C₃H₈) were not detected at any of the locations sampled by the data (poleward of 42 °N): 3-σ upper limits of ~10 ppbv at 10 mbar were derived at 62 °N inside Jupiter’s NAR, which is ~2.5 times the MP17 predicted abundance. The non-detection of propane could, in part, be explained by the vertical sensitivity of its mid-infrared emission lines to deeper pressures, where there is negligible auroral-related heating to warm the line forming region. The results of this work strongly advocate for development of ion-neutral chemistry models of Jupiter’s polar stratosphere to quantify how strong auroral-related heating and magnetospheric particles modify the reaction pathways that produce higher-order hydrocarbons.

Abstract:

Plain Language Summary: We present laboratory tests of a new instrument, the High‐resolution Volatiles and Minerals Moon Mapper ( H V M 3 ${\mathrm{H}\mathrm{V}\mathrm{M}}^{3}$ ). H V M 3 ${\mathrm{H}\mathrm{V}\mathrm{M}}^{3}$ will launch onboard the National Aeronautics and Space Administration's Lunar Trailblazer mission. It is an imaging spectrometer that will measure the spectrum of reflected sunlight in visible and infrared wavelengths for every pixel of an image. Scientists will interpret these spectra with the goal of measuring how water and ice are distributed across the lunar surface. Our laboratory tests indicate that the instrument is sensitive enough to measure small changes in the content of water on the lunar surface. We find the instrument capable of measuring areas of the Moon that are in permanent shadow using light reflected from neighboring surfaces like crater walls.

Abstract:

The Lunar Trailblazer mission launched in February of 2025 with the goal of characterizing lunar surface water through a targeted campaign. One instrument on the mission, the Lunar Thermal Mapper (LTM), was tasked with measuring the surface temperature to compare with maps of the form and abundance of water on the lunar surface. LTM's secondary science goals were to identify regolith composition and thermophysical properties as exhibited by mid‐infrared spectral features. Here we show the utility of LTM in distinguishing lunar regolith composition with its 11 narrow bands. Five spectral parameter products were developed to aid in early identification of regions of interest for follow‐on spectral analyses. These products include the Christiansen feature (CF) value, weighted absorption center (WAC) value, WAC band depth, Transparency Roll‐off, and a Diviner CF value equivalent. These products would be used mainly to flag these regions for more detailed follow‐up study with the entire spectral capabilities of the mission instrumentation. The Lunar Thermal Mapper (LTM) is one of two instruments on the Lunar Trailblazer mission launched in February 2025. LTM's primary goal is to provide surface temperature measurements for the lunar surface, in particular for identifying and mapping water on the Moon. LTM is also capable of identifying the compositional and physical properties of different rocks on the surface. Here, we test those capabilities and determine five methods for quickly distinguishing bulk properties of the lunar rocks that can be used by the community to identify regions of interest for further investigation. Mid‐infrared compositional parameters were created and tested for the Lunar Trailblazer mission Spectral parameters can distinguish bulk silicate mineralogy, and identify regions of compositional interest The Christiansen feature roll‐off parameter can provide an initial identification of areas with distinct thermophysical properties Mid‐infrared compositional parameters were created and tested for the Lunar Trailblazer mission Spectral parameters can distinguish bulk silicate mineralogy, and identify regions of compositional interest The Christiansen feature roll‐off parameter can provide an initial identification of areas with distinct thermophysical properties