Planetary atmosphere observation analysis

Abstract:

The loss of water from Mars to space is thought to result from the transport of water to the upper atmosphere, where it is dissociated to hydrogen and escapes the planet. Recent observations have suggested large, rapid seasonal intrusions of water into the upper atmosphere, boosting the hydrogen abundance. We use the Atmospheric Chemistry Suite on the ExoMars Trace Gas Orbiter to characterize the water distribution by altitude. Water profiles during the 2018–2019 southern spring and summer stormy seasons show that high-altitude water is preferentially supplied close to perihelion, and supersaturation occurs even when clouds are present. This implies that the potential for water to escape from Mars is higher than previously thought.

Abstract:

We report the first detection of stratospheric propadiene (CH 2 CCH 2 ) and propene (C 3 H 6 ) at Jupiter’s mid-to-high northern latitudes using IRTF-TEXES measurements recorded on March 5-6, 2025. Using radiative transfer software to quantitatively test for the presence of propadiene and propene, we report a > 12- σ detection of propadiene and a > 17- σ detection of propene at high latitudes inside Jupiter’s auroral region, where the species are most concentrated. For example, at 62 °N (planetocentric) inside Jupiter’s northern auroral region (henceforth ‘NAR’), we derive a 1-mbar propadiene abundance of 2.0 ± 0.2 ppbv, which is 40 ± 3 higher than abundances predicted by the Moses and Poppe (2017) photochemical model (henceforth ‘MP17’), and significantly higher than the 1.2-pbbv upper limit abundance derived at 42 °N (the lowest latitude sampled by the observations). Similarly, we derive a 1-mbar propene abundance 8.1 ± 0.5 ppbv at 62 °N inside Jupiter’s NAR, which is 28 ± 2 higher than the MP17 predicted abundance and significantly higher than the 6-ppbv 1-mbar upper limit abundance derived at 42 °N. The fact that propadiene and propene are most enriched inside Jupiter’s NAR strongly suggests that perturbations to the chemistry by auroral-related heating and exogenous ions/electrons are responsible for their significant enrichment, as has been observed for other unsaturated/aromatic hydrocarbon species. Spectral features of propane (C 3 H 8 ) were not detected at any of the locations sampled by the data (poleward of 42 °N): 3- σ upper limits of ∼ 10 ppbv at 10 mbar were derived at 62 °N inside Jupiter’s NAR, which is ∼ 2.5 times the MP17 predicted abundance. The non-detection of propane could, in part, be explained by the vertical sensitivity of its mid-infrared emission lines to deeper pressures, where there is negligible auroral-related heating to warm the line forming region. The results of this work strongly advocate for development of ion-neutral chemistry models of Jupiter’s polar stratosphere to quantify how strong auroral-related heating and magnetospheric particles modify the reaction pathways that produce higher-order hydrocarbons.

Abstract:

Cassini observed Jupiter during its 2000–2001 gravity-assist flyby, acquiring a valuable set of Visible and Infrared Mapping Spectrometer (VIMS) observations over a wide range of viewing geometries and observing conditions. These data comprise visible and infrared spectral cubes covering the VIS channel from 0.35 to 1.05 µm and the IR channel from 0.9 to 5.1 µm. We present a calibrated catalog of these Jupiter VIMS observations,  excluding satellite-targeted observations, designed to provide a homogeneous and validated set of spectral products for future Jovian studies.Starting from the raw archive cubes, we developed a processing workflow that combines ISIS/SPICE-based geometry recovery with dedicated radiometric calibration procedures for both VIMS channels. The final products are delivered as multi-extension FITS files containing calibrated I/F spectral cubes, wavelength and FWHM vectors, and geometry backplanes for incidence, emission, and phase angles, planetocentric latitude, positive-east longitude, pixel resolution, and azimuth angle. The workflow also addresses several issues affecting the original data set, including saturation, VIS pointing-related offsets between radiometric cubes and geometric backplanes, channel-dependent dark-signal artifacts, and a subset of IR approach-phase for which the standard ISIS calibration pipeline can produce over-scaled reflected spectra.The resulting catalog provides a uniform, documented, validated, and publicly available set of Cassini/VIMS Jupiter products. By combining calibrated VIS and IR cubes with wavelength information and geometry backplanes, these products facilitate a wide range of applications in the study of Jupiter and its atmosphere.