Acuminated fluorescence of Er3 + centres in endohedral fullerenes through the incarceration of a carbide cluster
Chemical Physics Letters 476:1-3 (2009) 41-45
Abstract:
Photoluminescence spectroscopic measurements have allowed the acquisition of high resolution spectra at low temperature for the endohedral metallofullerenes, Er2 @ C82 (isomer I) and Er2 C2 @ C82 (isomer I). The characteristic emission in the 1.5-1.6 μm region corresponds to the 4 I13 / 2 (m) → 4 I15 / 2 (n) transitions of the Er3 + ion for both molecules. The emission arising from Er2 C2 @ C82 (I) appears acuminated (narrow lines that taper to a point) when compared with that of Er2 @ C82 (I). The Er2 C2 @ C82 (I) emission linewidths are comparable to those found in crystals, making this molecule of interest for applications where accessible, well-defined quantum states are required. © 2009 Elsevier B.V. All rights reserved.ChemInform Abstract: Synthesis of Fullerene Dimers with Controllable Length
ChemInform Wiley 40:23 (2009) no-no
Magnetic field sensing beyond the standard quantum limit using 10-spin NOON states.
Science 324:5931 (2009) 1166-1168
Abstract:
Quantum entangled states can be very delicate and easily perturbed by their external environment. This sensitivity can be harnessed in measurement technology to create a quantum sensor with a capability of outperforming conventional devices at a fundamental level. We compared the magnetic field sensitivity of a classical (unentangled) system with that of a 10-qubit entangled state, realized by nuclei in a highly symmetric molecule. We observed a 9.4-fold quantum enhancement in the sensitivity to an applied field for the entangled system and show that this spin-based approach can scale favorably as compared with approaches in which qubit loss is prevalent. This result demonstrates a method for practical quantum field sensing technology.Magnetic field sensing beyond the standard quantum limit using 10-spin noon states
Science 324:5931 (2009) 1166-1168