Prof Arzhang Ardavan

Abstract:

The photoluminescence study of the Er3+ ion in ErSc 2N@C80 and Er2ScN@C80 fullerenes in the temperature range of 5 K to 80 K is presented. New emission peaks are observed for both fullerenes above 20 K. These peaks arise from thermally populated crystal-field levels of the excited state. An anomalous behaviour of the PL peak area is observed with an increasing temperature which reveals an internal rearrangement of the cluster ErSc2N in ErSc 2N@C80. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Abstract:

The fact that the formula used by Hannay in the preceding Comment [J. Opt. Soc. Am. A25, 2165 (2008)] is "from a standard text on electrodynamics" neither warrants that it is universally applicable nor that it is unequivocally correct. We have explicitly shown [J. Opt. Soc. Am. A25, 543 (2008)] that, since it does not include the boundary contribution toward the value of the field, the formula in question is not applicable when the source is extended and has a distribution pattern that rotates faster than light in vacuo. The neglected boundary term in the retarded solution to the wave equation governing the electromagnetic field forms the basis of diffraction theory. If this term were identically zero, for the reasons given by Hannay, the diffraction of electromagnetic waves through apertures on a surface enclosing a source would have been impossible.

Abstract:

Dynamic nuclear polarization transfers spin polarization from electrons to nuclei. We have achieved this by a new method, simultaneously exciting transitions of electronic and nuclear spins. The efficiency of this technique improves with increasing magnetic field. Experimental results are shown for N@C 60 with continuous-wave microwaves, which can be expected to produce even higher polarization than the corresponding pulsed techniques for electron spins greater than 1/2. The degree of nuclear polarization in this case can be easily monitored through the intensities of the well-resolved hyperfine components in the electron paramagnetic resonance spectrum. The nuclear spin-lattice relaxation time is orders of magnitude longer than that of the electrons. © 2008 Springer-Verlag.

Abstract:

Motivated by the possibility of observing photoluminescence and electron paramagnetic resonance from the same species located within a fullerene molecule, we initiated an EPR study of Er3+ in ErSc2N@C80. Two orientations of the ErSc2N rotor within the C80 fullerene are observed in EPR, consistent with earlier studies using photoluminescence excitation (PLE) spectroscopy. For some crystal field orientations, electron spin relaxation is driven by an Orbach process via the first excited electronic state of the 4I(15/2) multiplet. We observe a change in the relative populations of the two ErSc2N configurations upon the application of 532 nm illumination, and are thus able to switch the majority cage symmetry. This photoisomerization, observable by both EPR and PLE, is metastable, lasting many hours at 20 K.