Andrew Boothroyd

Abstract:

The magnetic ground state of a single crystalline bilayered manganite La1.1 Sr1.9 Mn2 O7 is investigated using bulk magnetic measurements. Besides large relaxation times, memory effects reminiscent of that seen in spin glasses are also observed both in the field cooled and zero field cooled measurement protocols. These indicate that this system is not a canted antiferromagnet as was reported earlier, but on the contrary has an inhomogenous magnetic ground state arising as a consequence of phase separation. We also report the observation of sharp metamagnetic steps in this bilayered manganite, similar to that seen in phase separated three-dimensional perovskites. © 2006 The American Physical Society.

Abstract:

Magnetoelectronic phase separation plays an integral part in many recent advances in the understanding of correlated electron systems. We have studied the magnetically phase separated material La1-x Srx Co O3 and observe unambiguous evidence of magnetic interactions between hole-rich ferromagnetic clusters and the neighboring hole poor matrix. We suggest that this mechanism detected here plays an important role in the rich electrical and magnetic properties of La1-x Srx Co O3. © 2006 The American Physical Society.

Abstract:

The structure of bilayer manganite LaSr2Mn2O7 has been investigated under high pressure using synchrotron and laboratory X-rays in the angle-dispersive X-ray diffraction geometry up to 35 GPa at ambient temperature. The Rietveld refinement results of the powder diffraction data show a crossover between the axial and equatorial Mn-O bond length values and a significant suppression of Jahn-Teller (JT) distortion around 16 GPa. Our results imply that a re-entrant behavior in LaSr2Mn2O7, which shows equality in all the three Mn-O bond length values around 16 GPa similar to ambient conditions, may dramatically alter the orbital ordering. Further, the P-V data for the bilayer compounds indicate that the additional substitution of La³⁺ for Sr²⁺ lowers the bulk modulus and enhances lattice softening. © 2006 Elsevier Ltd. All rights reserved.