Prof Radu Coldea

Abstract:

the deposited package contains resistivity and x-ray diffraction data on the layered potassium-iridate materials KxIryO2 We report structural studies of the spin-orbit Mott insulator family KxIryO2, with triangular layers of edge-sharing IrO6 octahedra bonded by potassium ions. The potassium content acts as a chemical tuning parameter to control the amount of charge in the Ir-O layers. Unlike the isostructural families with Ir replaced by Co or Rh (y=1), which are metallic over a range of potassium compositions x, we instead find insulating behaviour with charge neutrality achieved via iridium vacancies, which order in a honeycomb supercell above a critical composition. By performing density functional theory calculations we attribute the observed behaviour to a subtle interplay of crystal-field environment, local electronic correlations and strong spin-orbit interaction at the Ir4+ sites, making this structural family a candidate to display Kitaev magnetism in the experimentally unexplored regime that interpolates between triangular and honeycomb structures.

Abstract:

The deposited package contains magnetic susceptibility, muon spin relaxation, powder inelastic neutron scattering and pulsed-field magnetization data of the honeycomb Kitaev magnet alpha-Li2IrO3. The readme file inside the .zip archive contains detailed information about the individual file formats in the data archive.

Abstract:

We report inelastic neutron scattering measurements of the magnetic excitations in Ba2CuTeO6, proposed by ab initio calculations to magnetically realize weakly coupled antiferromagnetic two-leg spin-1/2 ladders. Isolated ladders are expected to have a singlet ground state protected by a spin gap. Ba2CuTeO6 orders magnetically, but with a small Neel temperature relative to the exchange strength, suggesting that the interladder couplings are relatively small and only just able to stabilize magnetic order, placing Ba2CuTeO6 close in parameter space to the critical point separating the gapped phase and Neel order. Through comparison of the observed spin dynamics with linear spin wave theory and quantum Monte Carlo calculations, we propose values for all relevant intra- and interladder exchange parameters, which place the system on the ordered side of the phase diagram in proximity to the critical point. We provide further cross-checks of the extracted parameters by comparison with high field magnetization data.