Harrison Nicholls (he/him)

Abstract:

The effect of enhanced UV irradiation associated with stellar flares on the atmospheric composition and temperature of gas giant exoplanets was investigated. This was done using a 1D radiative-convective-chemical model with self-consistent feedback between the temperature and the non-equilibrium chemistry. It was found that flare-driven changes to chemical composition and temperature give rise to prolonged trends in evolution across a broad range of pressure levels and species. Allowing feedback between chemistry and temperature plays an important role in establishing the quiescent structure of these atmospheres, and determines their evolution due to flares. It was found that cooler planets are more susceptible to flares than warmer ones, seeing larger changes in composition and temperature, and that temperature–chemistry feedback modifies their evolution. Long-term exposure to flares changes the transmission spectra of gas giant atmospheres; these changes differed when the temperature structure was allowed to evolve self-consistently with the chemistry. Changes in spectral features due to the effects of flares on these atmospheres can be associated with changes in composition. The effects of flares on the atmospheres of sufficiently cool planets will impact observations made with JWST. It is necessary to use self-consistent models of temperature and chemistry in order to accurately capture the effects of flares on features in the transmission spectra of cooler gas giants, but this depends heavily on the radiation environment of the planet.

Abstract:

The geochemical evolution of long-lived magma oceans is strongly regulated by volatile exchange between the molten mantle and the atmosphere. For planets inside the runaway-greenhouse limit, this coupled evolution can persist for billions of years, governing bulk density, surface conditions, and long-term geodynamics. However, most existing studies assume Earth-like (oxidized) conditions and neglect the influence of redox state on melt thermodynamics and volatile release. We quantify how experimentally derived, oxygen-fugacity-dependent melting curves implemented within the coupled interior-atmosphere framework PROTEUS propagate into the thermal structure, melt fraction, and rheological evolution of rocky exoplanet interiors, applying this to the short-period super-Earth GJ 1132 b. We find strongly non-linear thermal responses to variations in melting curves. In volatile-poor systems, reduced meltingcurves ( f O2 ≤ IW) promote earlier deep-mantle crystallisation relative to oxidised (IW + 2.0) and Earth-like (IW+4.0) cases (range IW−4.0 to IW+4.0), favouring late-stage surface magma oceans sustained by greenhouse warming, while oxidized melting curves maintain higher melt fractions and a vertically extended magma ocean. Reduced mantles produce massive H2-CO-rich atmospheres; oxidized mantles favour thinner H2O-CO2 envelopes. In volatile-rich systems, the interior reaches radiative equilibrium at high melt fractions, sustaining a steady-state global magma ocean in which melting curve variations do not significantly influence solidification timing. This indicates a hierarchical control: volatile inventory and surface oxygen fugacity act as the primary regulators of thermal state, while oxygen-fugacity-dependent melting relations provide a secondary modulation. These contrasting regimes produce distinct atmospheric compositions and formation timescales, offering testable spectral predictions for close-in rocky exoplanets evaluable with forthcoming JWST observations.