Mesoscopic and Microscopic Phase Segregation in Manganese Perovskites
(2000)
Mesoscopic and Microscopic Phase Segregation in Manganese Perovskites
ArXiv cond-mat/0006190 (2000)
Abstract:
Mesoscopic (500-2000 Angstrom) and microscopic (5-20 Angstrom) phase segregation with temperature and magnetic field was studied in the model manganite Pr0.7Ca0.3MnO3 by high-resolution neutron diffraction and inelastic neutron scattering. Intra-granular strain-driven mesoscopic segregation between two insulating phases, one of which is charge ordered (CO), sets in below the CO temperature in zero field. The CO phase orders antiferromagnetically, while the other insulating phase shows spin-glass behavior. After field-induced metallization, the CO phase coexists with a ferromagnetic metallic phase.A powder diffraction study of the phase transition in LaAlO3
Zeitschrift fur Kristallographie 215:9 (2000) 536-541
Abstract:
The structure of LaAlO3 has been investigated around the phase transition at T(c) ≃ 800 K by neutron powder diffraction in vacuum and by X-ray powder diffraction under nitrogen atmosphere as well as by a very high resolution synchrotron experiment in air. The results were analysed in frame of the Landau theory using the fluctuation-dissipation theorem to relate the susceptibility to the atomic displacement parameters. The room temperature structure is a rhombohedrally distorted perovskite structure, space group R3c, which undergoes a transition to the ideal perovskite structure, space group Pm3m, at high temperatures. The order parameter is a rotation of the O6-octahedron described by one χ(O)-parameter. This parameter and the spontaneous strain (c/a - √6), as well as the relevant atomic displacement parameter U(op) 11(O) in the order parameter system, show a critical behaviour in agreement with a second order phase transition. Although the critical exponents of the order parameter and strain show the expected coupling behaviour, there is a striking difference of the transition temperature: the metric becomes cubic roughly 30 K below the proper T(c). This is related to spontaneous formation of domains imposing the average cubic symmetry via internal stresses.Charge, orbital and magnetic ordering in La0.333 Ca0.667 MnO3
Materials Science Forum 321 (2000)
Abstract:
The magnetic superstructure in La0.333Ca0.667MnO3 has been solved using neutron powder diffraction analysis and two models (a `Stripe' and a `Wigner crystal' one) have been proposed for the charge and orbital ordering associated with it. The observed antiferromagnetic superreflections can be described by a collinear model where the spins are predominantly oriented along the a axis. However a considerable improvement in the Retvield refinement is yielded by a non-collinear model within the `Wigner' arrangement of the charges.Crystal and electronic structures of superconducting YSr2 Cu3 O6+x
Proceedings of SPIE - The International Society for Optical Engineering 4058 (2000) 12-17