The PAH 3.4 micron feature as a tracer of shielding in the Orion Bar and NGC 6240
Monthly Notices of the Royal Astronomical Society Oxford University Press (OUP) (2025) staf2047
Abstract:
<jats:title>Abstract</jats:title> <jats:p>We have carried out a detailed analysis of the 3.4 μm spectral feature arising from Polycyclic Aromatic Hydrocarbons (PAH), using JWST archival data. For the first time in an external galaxy (NGC 6240), we have identified two distinct spectral components of the PAH 3.4 μm feature: a shorter wavelength component at 3.395 μm, which we attribute to short aliphatic chains tightly attached to the aromatic rings of the PAH molecules; and a longer wavelength feature at 3.405 μm that arises from longer, more fragile, aliphatic chains that are weakly attached to the parent PAH molecule. These longer chains are more easily destroyed by far-ultraviolet photons (&gt;5eV) and PAH thermal emission only occurs where PAH molecules are shielded from more energetic photons by dense molecular gas. We see a very strong correlation in the morphology of the PAH 3.395 μm feature with the PAH 3.3 μm emission, the latter arising from robust aromatic PAH molecules. We also see an equally strong correlation between the PAH 3.405 μm morphology and the warm molecular gas, as traced by H2 vibrational lines. We show that the flux ratio PAH 3.395/PAH 3.405 &lt; 0.3 corresponds strongly to regions where the PAH molecules are shielded by dense molecular gas, so that only modestly energetic UV photons penetrate to excite the PAHs. Our work shows that PAH 3.405 μm and PAH 3.395 μm emission features can provide robust diagnostics of the physical conditions of the interstellar medium in external galaxies, and can be used to quantify the energies of the photon field penetrating molecular clouds.</jats:p>Multi-modal atmospheric characterization of $β$ Pictoris b: Adding high-resolution continuum spectra from GRAVITY
(2025)
No TiO detected in the hot-Neptune-desert planet LTT-9779 b in reflected light at high spectral resolution
Astronomy & Astrophysics EDP Sciences (2025)
Abstract:
LTT-9779,b is an inhabitant of the hot-Neptune desert and one of only a few planets with a measured high albedo. Characterising the atmosphere of this world is the key to understanding the processes that dominate in reducing the number of short-period intermediate-mass planets that create the hot-Neptune desert. We aim to characterise the reflected light of LTT-9779,b at high spectral resolution to break the degeneracy between clouds and atmospheric metallicity. This is key to interpreting its mass-loss history, which might illuminate how it kept its place in the desert. We used the high-resolution cross-correlation spectroscopy technique on four half-nights of ESPRESSO observations in 4-UT mode (16.4 m effective mirror) to constrain the reflected-light spectrum of łttb. We did not detect the reflected-light spectrum of łttb, although these data had the expected sensitivity at the level 100 ppm. Injection tests of the post-eclipse data indicated that TiO should have been detected for a range of different equilibrium chemistry models. Therefore, this non-detection suggests TiO depletion in the western hemisphere, but this conclusion is sensitive to temperature, which affects the chemistry in the upper atmosphere and the reliability of the line list. Additionally, we were able to constrain the top of the western cloud deck to P_ top, western bar and the top of the eastern cloud deck to P_ top, eastern bar, which is consistent with the predicted altitude of MgSiO_3 and Mg_2SiO_4 clouds from JWST NIRISS/SOSS. While we did not detect the reflected-light spectrum of łttb, we verified that this technique can be used in practice to characterise the reflected light of exoplanets at high spectral resolution when their spectra contain a sufficient number of deep spectral lines. Therefore, this technique may become an important cornerstone of exoplanet characterisation with the ELT and beyond.No TiO detected in the hot Neptune-desert planet LTT-9779 b in reflected light at high spectral resolution
(2025)
Chasing the storm: Investigating the application of high-contrast imaging techniques in producing precise exoplanet light curves
(2025)