Magnetism for Intelligent Devices (MIND)

Abstract:

We present a systematic study of atmospheric chemical vapor deposition growth of carbon nanotubes (CNTs) on patterned, transition metal/GaAs samples employing methane as the carbon feedstock. Controlled CNT growth was found to occur from the exposed metal-semiconductor interface, rather than from the metal or semiconductor surfaces themselves. A fast sample loading system allowed for a minimization of the exposure to high temperatures, thereby preventing excessive sample damage. The optimum growth temperature for CrNi/GaAs interfaces is 700 °C (at a methane flow rate of 700 sccm). Possible growth scenarios involving the Ni-As-Ga system and its interaction with C is discussed. Raman spectroscopy of the CNTs revealed the presence of pentagon-heptagon defects. Closer analysis of the spectra points towards a mixture of so-called Haeckelite CNTs. © 2011 John Wiley & Sons, Ltd.