Oxide electronics

Abstract:

Cu and C substitution for Hg in Hg-based cuprate superconductors is discussed. The large Hg Debye-Waller factor usually obtained from refinements based on diffraction data should be interpreted as an indication of carbon substitution for the Hg cations. This assumption is corroborated by HREM, powder x-ray anomalous dispersion, and powder neutron diffraction investigations. © 1995 Plenum Publishing Corporation.

Abstract:

The crystal structure of the newly discovered double-Hg-layer copper oxide superconductor (Hg, Pr)2Ba2(Y, Ca)Cu2O8-δ was studied as a function of chemical doping using neutron and electron diffraction and high-resolution transmission electron microscopy (HREM). Rietveld refinements of the structural parameters from neutron powder diffraction data indicate that the oxygen site O3 on the mercury plane is highly defective, being both partially occupied and displaced from the high-symmetry position. The variable concentration of oxygen vacancies partially compensates for the cation doping and, together with the O3 displacement field, makes some of the Hg atoms acquire an unusual pyramidal coordination. HREM images confirm that the structure is of the '2212' type, with very few defects. In some grains, faint superstructure reflections were evidenced by electron diffraction, suggesting that both the oxygen vacancies and the O3 displacement field may order at least on a local scale. © 1995.

Abstract:

We have realized planar tunnel junctions using both Y123 and Y124 single crystals as base electrodes and Pb as counterelectrode. The crystals, with T c =90 K (Y123) and T c =80 K (Y124), have been chemically etched and natural barriers were formed by a short air exposure. We have compared the tunneling spectra obtained on both systems. The features at about±18mV of the Y123 compound are still observed in the Y124, while the low-bias structures at ±5 mV are not present in the tunneling characteristics of the Y124 system. Linearity of the background conductance is also observed, with less steep slopes in Y124 that might indicate a reduced interlayer coupling in this system. © 1994 Societá Italiana di Fisica.