Quantum spin dynamics

Abstract:

Superposition and entanglement are uniquely quantum phenomena. Superposition incorporates a phase that contains information surpassing any classical mixture. Entanglement offers correlations between measurements in quantum systems that are stronger than any that would be possible classically. These give quantum computing its spectacular potential, but the implications extend far beyond quantum information processing. Early applications may be found in entanglement-enhanced sensing and metrology. Quantum spins in condensed matter offer promising candidates for investigating and exploiting superposition and entanglement, and enormous progress is being made in quantum control of such systems. In gallium arsenide (GaAs), individual electron spins can be manipulated and measured, and singlet-triplet states can be controlled in double-dot structures. In silicon, individual electron spins can be detected by ionization of phosphorus donors, and information can be transferred from electron spins to nuclear spins to provide long memory times. Electron and nuclear spins can be manipulated in nitrogen atoms incarcerated in fullerene molecules, which in turn can be assembled in ordered arrays. Spin states of charged nitrogen vacancy centres in diamond can be manipulated and read optically. Collective spin states in a range of materials systems offer scope for holographic storage of information. Conditions are now excellent for implementing superposition and entanglement in spintronic devices, thereby opening up a new era of quantum technologies.

Abstract:

The synthesis, structure, and magnetic properties of a ligand-modified Mn(4) dicubane single-molecule magnet (SMM), [Mn(4)(Bet)(4)(mdea)(2)(mdeaH)(2)](BPh(4))(4), are presented, where the cationic SMM units are significantly separated from neighboring molecules in the crystal lattice. There are no cocrystallized solvate molecules, making it an ideal candidate for single-crystal magnetization hysteresis and high-frequency electron paramagnetic resonance studies. Increased control over intermolecular interactions in such materials is a crucial factor in the future application of SMMs.

Abstract:

A Mn(4) single-molecule magnet displays asymmetric Berry-phase interference patterns in the transverse-field (H(T)) dependence of the magnetization tunneling probability when a longitudinal field (H(L)) is present, contrary to symmetric patterns observed for H(L)=0. Reversal of H(L) results in a reflection of the transverse-field asymmetry about H(T)=0, as expected on the basis of the time-reversal invariance of the spin-orbit Hamiltonian which is responsible for the tunneling oscillations. A fascinating motion of Berry-phase minima within the transverse-field magnitude-direction phase space results from a competition between noncollinear magnetoanisotropy tensors at the two distinct Mn sites.