Quantum spin dynamics

Abstract:

We report high-field magneto transport measurements on beta''- BEDT-TTF4[(H3O)M(C2O4)(3)]C5H5N, where M = Ga3+, Cr3+ or Fe3+. In spite of the differing M ions, these compounds have very similar Fermi surfaces. We observe four distinct Shubnikov-de Haas frequencies, corresponding to four Fermi-surface pockets; the frequencies exhibit the additive relationship expected for a compensated semimetal. The compounds show paramagnetic behaviour and no superconductivity down to 0.5 K, in contrast to other materials of the same family with different solvent molecules. (C) 2003 Elsevier B.V. All rights reserved.

Abstract:

We show that the coexistence of a quasi-two-dimensional Fermi-surface exhibiting Landau quantisation and a charge-density wave leads to a screening of electromagnetic fields at the sample Surface. Hall potential experiments demonstrate that this screening is responsible for some of the unusual phenomena observed in the high-field CDWx state of alpha-(BEDT-TTF)(2)KHg(SCN)(4).

Abstract:

We applied magneto-optical techniques to investigate the electron spin resonance (ESR) spectra of single crystal and powder samples of the organic superconductor beta"-(BEDT- TTF)(4)[(H3O)Fe (C2O4)(3)]C6H5CN. Data were obtained in magnetic fields up to 10 Tesla using both cylindrical and rectangular resonators at 55, 63 and 72 GHz and transmission measurements at 95 and 190 GHz with field modulation. Analysis of the high field-high frequency ESR lines for different field orientations and temperatures allows the determination of the g-value anisotropy and the zero-field splitting parameters for the Fe3+ ions (S = 5/2), showing that they occupy a site with distorted octahedral symmetry. The temperature and frequency dependences of the magneto-optical spectra are used to identify the nature of the interaction between localised Fe spins and between the local moments and the delocalised carriers.

Abstract:

We report high-field magnetotransport measurements oil beta"-(BEDT-TTF)(4)[(H3O)M(C2O4)(3)], solvent, where M=Ga3+, Cr3+ and Fe3+ and solvent=C5H5N. In spite of their differing transition metal-ions, M, the three compounds exhibit similar magnetic quantum oscillation spectra superimposed on a positive magnetoresistance. At least four independent quantum oscillation frequencies have been identified, corresponding to two different hole and electron pockets of the Fermi surface which follow the rules of a compensated metal. Observation of the small pockets could be the result of the Fermi surface reconstruction induced by a possible density wave. The effective masses are very similar for different samples and for different pockets range between m(eff) approximate to 0.5 - 1.1 m(e) whereas the Dingle temperatures varies between T-D approximate to 1.4 - 4 K. At low temperature, the longitudinal magnetoresistance violates Kohler's rule, suggesting that the interlayer transport in these quasi-2D systems cannot be related to a single scattering time and that the disorder plays an important role.

Abstract:

We present the results of numerical calculations of the energy levels and eigenfunctions of finite sections of a tight-binding square lattice in the presence of a perpendicular magnetic field. The energy spectrum of such a system, plotted as a function of magnetic field, resembles the Hofstadter butterfly found for the infinite system. In high magnetic fields, each eigenstate carries a persistent current which has a chirality associated with whether the eigenstate exists in the bulk or the edge of the system. We present simulations of electric dipole transitions between the chirally distinguished states for an isotropic lattice. These transitions correspond to harmonics in the cyclotron resonance.