Superstructure and Correlated Na+ Hopping in a Layered Mg-Substituted Sodium Manganate Battery Cathode are Driven by Local Electroneutrality

Chemistry of Materials American Chemical Society (ACS) 35:24 (2023) 10564-10583

Authors:

Euan N Bassey, Ieuan D Seymour, Joshua D Bocarsly, David A Keen, Guido Pintacuda, Clare P Grey

Siliceous zeolite-derived topology of amorphous silica

Communications Chemistry Nature Research 6:1 (2023) 269

Authors:

Hirokazu Masai, Shinji Kohara, Toru Wakihara, Yuki Shibazaki, Yohei Onodera, Atsunobu Masuno, Sohei Sukenaga, Koji Ohara, Yuki Sakai, Julien Haines, Claire Levelut, Philippe Hébert, Aude Isambert, David A Keen, Masaki Azuma

Abstract:

Abstract The topology of amorphous materials can be affected by mechanical forces during compression or milling, which can induce material densification. Here, we show that densified amorphous silica (SiO2) fabricated by cold compression of siliceous zeolite (SZ) is permanently densified, unlike densified glassy SiO2 (GS) fabricated by cold compression although the X-ray diffraction data and density of the former are identical to those of the latter. Moreover, the topology of the densified amorphous SiO2 fabricated from SZ retains that of crystalline SZ, whereas the densified GS relaxes to pristine GS after thermal annealing. These results indicate that it is possible to design new functional amorphous materials by tuning the topology of the initial zeolitic crystalline phases

Local structure and lithium-ion diffusion pathway of cubic Li7La3Zr2O12 studied by total scattering and the Reverse Monte Carlo method

Journal of Materials Chemistry A: materials for energy and sustainability Royal Society of Chemistry 11:46 (2023) 25516-25533

Authors:

Haolai Tian, Guanqun Cai, Lei Tan, He Lin, Anthony E Phillips, Isaac Abrahams, David A Keen, Dean S Keeble, Andy Fiedler, Junrong Zhang, Xiang Yang Kong, Martin T Dove

Abstract:

The cubic phase of Li 7 La 3 Zr 2 O 12 shows fast diffusion of the lithium ions. Combining total scattering measurements analysed by the RMC method with molecular dynamics simulations gives a detailed picture of the distribution of the Li + ions.

Barriers to healthcare-worker adherence to infection prevention and control practices in British Columbia during the coronavirus disease 2019 (COVID-19) pandemic: A cross-sectional study

Infection Control and Hospital Epidemiology Cambridge University Press 45:4 (2023) 474-482

Authors:

Brooke T Cheng, R Ayesha Ali, Jun Chen Collet, Tara Donovan Towell, Guanghong Han, Dave Keen, Ka Wai Leung, Julie Mori, Jocelyn A Srigley

Abstract:

OBJECTIVE: The coronavirus disease 2019 (COVID-19) pandemic highlighted the importance of robust infection prevention and control (IPAC) practices to maintain patient and staff safety. However, healthcare workers (HCWs) face many barriers that affect their ability to follow these practices. We identified barriers affecting HCW adherence to IPAC practices during the pandemic in British Columbia, Canada. DESIGN: Cross-sectional web-based survey. SETTING: Acute care, long-term care or assisted living, outpatient, mental health, prehospital care, and home care. PARTICIPANTS: Eligible respondents included direct-care providers and IPAC professionals working in these settings in all health authorities across British Columbia. METHODS: We conducted a web-based survey from August to September 2021 to assess respondent knowledge and attitudes toward IPAC within the context of the COVID-19 pandemic. Respondents were asked to rate the extent to which various barriers affected their ability to follow IPAC practices throughout the pandemic and to make suggestions for improvement. RESULTS: The final analysis included 2,488 responses; 36% of respondents worked in acute care. Overall, perceptions of IPAC practice among non-IPAC professionals were positive. The main self-perceived barriers to adherence included inadequate staffing to cover absences (58%), limited space in staff rooms (57%), multibed rooms (51%), and confusing messages about IPAC practices (51%). Common suggestions for improvement included receiving more support from IPAC leadership and clearer communication about required IPAC practices. CONCLUSIONS: Our findings highlight frontline HCW perspectives regarding priority areas of improvement for IPAC practices. They will inform policy and guideline development to prevent transmission of COVID-19 and future emerging infections.

Structural insights into hybrid immiscible blends of metal–organic framework and sodium ultraphosphate glasses

Chemical Science Royal Society of Chemistry (RSC) 14:42 (2023) 11737-11748

Authors:

Ashleigh M Chester, Celia Castillo-Blas, Roman Sajzew, Bruno P Rodrigues, Ruben Mas-Balleste, Alicia Moya, Jessica E Snelson, Sean M Collins, Adam F Sapnik, Georgina P Robertson, Daniel JM Irving, Lothar Wondraczek, David A Keen, Thomas D Bennett