Ultrafast Bragg coherent diffraction imaging of epitaxial thin films using deep complex-valued neural networks

npj Computational Materials Springer Nature 10:1 (2024) 24

Authors:

Xi Yu, Longlong Wu, Yuewei Lin, Jiecheng Diao, Jialun Liu, Jörg Hallmann, Ulrike Boesenberg, Wei Lu, Johannes Möller, Markus Scholz, Alexey Zozulya, Anders Madsen, Tadesse Assefa, Emil S Bozin, Yue Cao, Hoydoo You, Dina Sheyfer, Stephan Rosenkranz, Samuel D Marks, Paul G Evans, David A Keen, Xi He, Ivan Božović, Mark PM Dean, Shinjae Yoo, Ian K Robinson

Weyl metallic state induced by helical magnetic order

npj Quantum Materials Springer Nature 9:1 (2024) 7

Authors:

Jian-Rui Soh, Irián Sánchez-Ramírez, Xupeng Yang, Jinzhao Sun, Ivica Zivkovic, Jose Alberto Rodríguez-Velamazán, Oscar Fabelo, Anne Stunault, Alessandro Bombardi, Christian Balz, Manh Duc Le, Helen C Walker, J Hugo Dil, Dharmalingam Prabhakaran, Henrik M Rønnow, Fernando de Juan, Maia G Vergniory, Andrew T Boothroyd

Abstract:

In the rapidly expanding field of topological materials there is growing interest in systems whose topological electronic band features can be induced or controlled by magnetism. Magnetic Weyl semimetals, which contain linear band crossings near the Fermi level, are of particular interest owing to their exotic charge and spin transport properties. Up to now, the majority of magnetic Weyl semimetals have been realized in ferro- or ferrimagnetically ordered compounds, but a disadvantage of these materials for practical use is their stray magnetic field which limits the minimum size of devices. Here we show that Weyl nodes can be induced by a helical spin configuration, in which the magnetization is fully compensated. Using a combination of neutron diffraction and resonant elastic x-ray scattering, we find that below TN = 14.5 K the Eu spins in EuCuAs develop a planar helical structure which induces two quadratic Weyl nodes with Chern numbers C = ±2 at the A point in the Brillouin zone.

Superstructure and Correlated Na+ Hopping in a Layered Mg-Substituted Sodium Manganate Battery Cathode are Driven by Local Electroneutrality

Chemistry of Materials American Chemical Society (ACS) 35:24 (2023) 10564-10583

Authors:

Euan N Bassey, Ieuan D Seymour, Joshua D Bocarsly, David A Keen, Guido Pintacuda, Clare P Grey

Siliceous zeolite-derived topology of amorphous silica

Communications Chemistry Nature Research 6:1 (2023) 269

Authors:

Hirokazu Masai, Shinji Kohara, Toru Wakihara, Yuki Shibazaki, Yohei Onodera, Atsunobu Masuno, Sohei Sukenaga, Koji Ohara, Yuki Sakai, Julien Haines, Claire Levelut, Philippe Hébert, Aude Isambert, David A Keen, Masaki Azuma

Abstract:

Abstract The topology of amorphous materials can be affected by mechanical forces during compression or milling, which can induce material densification. Here, we show that densified amorphous silica (SiO2) fabricated by cold compression of siliceous zeolite (SZ) is permanently densified, unlike densified glassy SiO2 (GS) fabricated by cold compression although the X-ray diffraction data and density of the former are identical to those of the latter. Moreover, the topology of the densified amorphous SiO2 fabricated from SZ retains that of crystalline SZ, whereas the densified GS relaxes to pristine GS after thermal annealing. These results indicate that it is possible to design new functional amorphous materials by tuning the topology of the initial zeolitic crystalline phases

Local structure and lithium-ion diffusion pathway of cubic Li7La3Zr2O12 studied by total scattering and the Reverse Monte Carlo method

Journal of Materials Chemistry A: materials for energy and sustainability Royal Society of Chemistry 11:46 (2023) 25516-25533

Authors:

Haolai Tian, Guanqun Cai, Lei Tan, He Lin, Anthony E Phillips, Isaac Abrahams, David A Keen, Dean S Keeble, Andy Fiedler, Junrong Zhang, Xiang Yang Kong, Martin T Dove

Abstract:

The cubic phase of Li 7 La 3 Zr 2 O 12 shows fast diffusion of the lithium ions. Combining total scattering measurements analysed by the RMC method with molecular dynamics simulations gives a detailed picture of the distribution of the Li + ions.