Low-energy quasi-one-dimensional spin dynamics in charge-ordered La 2-xSrxNiO4

Physical Review B - Condensed Matter and Materials Physics 83:9 (2011)

Authors:

PG Freeman, D Prabhakaran, K Nakajima, A Stunault, M Enderle, C Niedermayer, CD Frost, K Yamada, AT Boothroyd

Abstract:

The low-energy spin excitations of La2-xSrxNiO 4, x=0.275 and 1/3, have been investigated by unpolarized- and polarized-inelastic neutron scattering from single crystals. A pattern of magnetic diffuse scattering is observed in both compositions and is consistent with quasi-one-dimensional AFM spin correlations along the charge stripes. Analysis of the energy line shape for x=1/3 indicates that the diffuse scattering is inelastic with a characteristic energy of 1.40±0.07 meV. There is no discernible difference between the diffuse scattering from x=0.275 and x=1/3, suggesting that it is an intrinsic property of the charge stripes. © 2011 American Physical Society.

Crystal growth of spin-ice pyrochlores by the floating-zone method

Journal of Crystal Growth 318:1 (2011) 1053-1056

Authors:

D Prabhakaran, AT Boothroyd

Abstract:

Single crystals of RE2Ti2O7 (RE=Y, Tb, Dy and Ho) have been grown by the floating-zone technique in an image furnace in a controlled atmosphere. The effect of annealing the crystals in different atmospheres was studied and found to be very important. Small amounts of Y were doped on the Dy site to study its effect on the spin-ice behaviour. Results for the structural parameters obtained by X-ray diffraction and magnetic properties of the crystals are reported. © 2010 Elsevier B.V. All rights reserved.

Floating-zone growth of Na0.8-yAyCoO2 (A=Ca, Sr) single crystals

Journal of Crystal Growth 318:1 (2011) 924-926

Authors:

D Prabhakaran, AT Boothroyd

Abstract:

Single crystals of Na0.8-yAyCoO2 (A=Ca, Sr; y=0.10.3) have been grown using the optical floating-zone method for the first time. We have determined the optimum growth conditions to grow the highest quality single crystals. Columnar growth behavior has been observed for the higher doped samples. The magnetic and structural ordering temperatures of the doped samples were found to vary considerably. Crown Copyright © 2010 Published by Elsevier B.V. All rights reserved.

Thermal amorphization of zeolitic imidazolate frameworks.

Angewandte Chemie (International ed. in English) 50:13 (2011) 3067-3071

Authors:

Thomas D Bennett, David A Keen, Jin-Chong Tan, Emma R Barney, Andrew L Goodwin, Anthony K Cheetham

Hour-glass magnetic spectrum in an insulating, hole-doped antiferromagnet

(2011)

Authors:

AT Boothroyd, P Babkevich, D Prabhakaran, PG Freeman