Utilizing total scattering to study the Jahn-Teller transition in La1-xCaxMnO3
Chapter in Tenth European Powder Diffraction Conference, De Gruyter (2007) 429-434
Magnetoelastic coupling and symmetry breaking in the frustrated antiferromagnet alpha-NaMnO2.
Phys Rev Lett 99:24 (2007) 247211
Abstract:
The magnetic and crystal structures of the alpha-NaMnO2 have been determined by high-resolution neutron powder diffraction. The system maps out a frustrated triangular spin lattice with anisotropic interactions that displays two-dimensional spin correlations below 200 K. Magnetic frustration is lifted through magneto-elastic coupling, evidenced by strong anisotropic broadening of the diffraction profiles at high temperature and ultimately by a structural phase transition at 45 K. In this low-temperature regime a three-dimensional antiferromagnetic state is observed with a propagation vector k=(1/2,1/2,0).Charge disproportionation and collinear magnetic order in the frustrated triangular antiferromagnet AgNiO2
(2007)
Charge disproportionation and collinear magnetic order in the frustrated triangular antiferromagnet AgNiO2
ArXiv 0710.2811 (2007)
Abstract:
We report a high-resolution neutron diffraction study of the crystal and magnetic structure of the orbitally-degenerate frustrated metallic magnet AgNiO2. At high temperatures the structure is hexagonal with a single crystallographic Ni site, low-spin Ni3+ with spin-1/2 and two-fold orbital degeneracy, arranged in an antiferromagnetic triangular lattice with frustrated spin and orbital order. A structural transition occurs upon cooling below 365 K to a tripled hexagonal unit cell containing three crystallographically-distinct Ni sites with expanded and contracted NiO6 octahedra, naturally explained by spontaneous charge order on the Ni triangular layers. No Jahn-Teller distortions occur, suggesting that charge order occurs in order to lift the orbital degeneracy. Symmetry analysis of the inferred Ni charge order pattern and the observed oxygen displacement pattern suggests that the transition could be mediated by charge fluctuations at the Ni sites coupled to a soft oxygen optical phonon breathing mode. At low temperatures the electron-rich Ni sublattice (assigned to a valence close to Ni2+ with S = 1) orders magnetically into a collinear stripe structure of ferromagnetic rows ordered antiferromagnetically in the triangular planes. We discuss the stability of this uncommon spin order pattern in the context of an easy-axis triangular antiferromagnet with additional weak second neighbor interactions and interlayer couplings.Orbital degeneracy removed by charge order in triangular antiferromagnet AgNiO2.
Phys Rev Lett 99:15 (2007) 157204