Professor Paolo G. Radaelli OSI

Abstract:

The crystal and magnetic structure of (La0.70Ca0.30)(CryMn1-y)O3 for y = 0.70, 0.50 and 0.15 has been investigated using neutron powder diffraction. The three samples crystallize in the Pnma space group at both 290 K and 5 K and exhibit different magnetic structures at low temperature. In (La0.70Ca0.30)(Cr0.70Mn0.30)O3, antiferromagnetic order with a propagation vector k = 0 sets in. The magnetic structure is Gx, i.e. of the G-type with spins parallel to the a-axis. On the basis of our Rietveld refinement and the available magnetisation data, we speculate that only Cr3+ spins order, whereas Mn4+ act as a random magnetic impurity. In (La0.70Ca0.30)(Cr0.50Mn0.50)O3 the spin order is still of type Gx, although the net magnetic moment is smaller. No evidence for magnetic order of the Mn ions is observed. Finally, in (La0.70Ca0.30)(Cr0.15Mn0.85)O3 a ferromagnetic ordering of the Mn spins takes place, whereas the Cr3+ ions act as random magnetic impurities with randomly oriented spins.

Abstract:

A position sensitive detector for epithermal neutrons is being developed as a tool for neutron resonance tomography at pulsed neutron sources. Neutron-scattering effects in the detector elements were investigated with GEANT4 simulations. The simulations show that the effect of neutron scattering is generally low, and can be further suppressed by proper choice of construction materials. © 2008 IOP Publishing Ltd.

Abstract:

The magnetic and crystal structures of the alpha-NaMnO2 have been determined by high-resolution neutron powder diffraction. The system maps out a frustrated triangular spin lattice with anisotropic interactions that displays two-dimensional spin correlations below 200 K. Magnetic frustration is lifted through magneto-elastic coupling, evidenced by strong anisotropic broadening of the diffraction profiles at high temperature and ultimately by a structural phase transition at 45 K. In this low-temperature regime a three-dimensional antiferromagnetic state is observed with a propagation vector k=(1/2,1/2,0).