Prof Christopher Ramsey

Abstract:

The increasing application of the Bayesian approach for the interpretation of radiocarbon dates over the past decade has led to the production of more precise chronologies for archaeological sites. This has highlighted the practical significance of some scientific aspects of radiocarbon dating. The potential importance of one of these, the sources of the carbon component of human bone collagen, is demonstrated by a recent application of radiocarbon dating in medieval Norwich. Crown © 2003 Published by Elsevier Ltd. All rights reserved.

Abstract:

Precision and accuracy in accelerator mass spectrometry (AMS) dating relies on the systematic reduction of errors at all stages of the dating process, from sampling to AMS measurement. With new AMS systems providing much better precision and accuracy for the final stage of the process, we need to review the process as a whole to test the accuracy of reported results. A new High Voltage Engineering Europa (HVEE) AMS system was accepted at Oxford in September 2002. Since then, the system has been in routine use for AMS dating and here we report on our experiences during the first year. The AMS system itself is known to be capable of making measurements on single targets to a precision of better than 0.2% for the 14C/13C ratio and better than 0.1% for the 13C/12C ratio. In routine operation, we measure known-age wood to a precision of just above 0.3%, including uncertainties in background and pretreatment. At these levels, the scatter in results is no higher than reported errors, suggesting that uncertainties of ±25 to ±30 14C yr can be reliably reported on single target measurements. This provides a test of all parts of the process for a particular material in a particular state of preservation. More generally, sample pretreatment should remove as much contamination as feasible from the sample while adding as little laboratory contamination as possible. For more complex materials, such as bone, there is clearly more work needed to prove good reproducibility and insignificant offsets in all circumstances. Strategies for testing accuracy and precision on unknown material are discussed here, as well as the possibilities of one day reaching precisions equivalent to errors of <±20 14C yr.

Abstract:

This paper reports on the performance of a new method of sample injection using the High Voltage Engineering Europa (HVEE) SO-110 ion source jointly developed between HVEE and Oxford. In order to use this source, we have developed a new gas handling system which works on the direct injection of carbon dioxide mixed into a continuous flow of helium. Preliminary work has also been carried out on online gas chromatography-accelerator mass spectrometry (GC-AMS). In this application, a GC is directly coupled to the AMS system using a GC-IRMS combustion interface and Nafion™ drier. We show here results for the measurement of natural abundance in separated compounds with good peak separation and precisions of about 10%. This type of system should be ideal for source apportionment studies, biomedical, and other similar work where high precision is not required but where sample sizes are very low.

Abstract:

Given the non-monotonic form of the radiocarbon calibration curve, the precision of single 14C dates on the calendar timescale will always be limited. One way around this limitation is through comparison of time-series, which should exhibit the same irregular patterning as the calibration curve. This approach can be employed most directly in the case of wood samples with many years growth present (but not able to be dated by dendrochronology), where the tree-ring series of unknown date can be compared against the similarly constructed 14C calibration curve built from known-age wood. This process of curve-fitting has come to be called "wiggle-matching." In this paper, we look at the requirements for getting good precision by this method: sequence length, sampling frequency, and measurement precision. We also look at 3 case studies: one a piece of wood which has been independently dendrochronologically dated, and two others of unknown age relating to archaeological activity at Silchester, UK (Roman) and Miletos, Anatolia (relating to the volcanic eruption at Thera).

Abstract:

The radiocarbon calibration curve IntCal04 extends back to 26 cal kyr B P. While several high-resolution records exist beyond this limit, these data sets exhibit discrepancies of up to several millennia. As a result, no calibration curve for the time range 26–50 cal kyr BP can be recommended as yet, but in this paper the IntCal04 working group compares the available data sets and offers a discussion of the information that they hold.