Exoplanet atmospheres

Abstract:

We have analyzed infrared spectra of Titan recorded by the Cassini Composite Infrared Spectrometer (CIRS) to measure the isotopic ratio ¹²C/¹³C in each of three chemical species in Titan's stratosphere: CH4, C2H2 and C2H6. This is the first measurement of ¹²C/¹³C in any C2 molecule on Titan, and the first measurement of ¹²CH4/¹³CH4 (non-deuterated) on Titan by remote sensing. Our spectra cover five widely-spaced latitudes, 65° S to 71° N and we have searched for both latitude variability of ¹²C/¹³C within a given species, and also for differences between the ¹²C/¹³C in the three gases. For CH4 alone, we find ¹²C / ¹³C = 76.6 ± 2.7 (1-σ), essentially in agreement with the ¹²CH4/¹³CH4 measured by the Huygens Gas Chromatograph/Mass Spectrometer instrument (GCMS) [Niemann, H.B., and 17 colleagues, 2005. Nature 438, 779-784]: 82.3 ± 1.0, and also with measured values in H¹³CN and ¹³CH3D by CIRS at lower precision [Bézard, B., Nixon, C., Kleiner, I., Jennings, D., 2007. Icarus 191, 397-400; Vinatier, S., Bézard, B., Nixon, C., 2007. Icarus 191, 712-721]. For the C2 species, we find ¹²C / ¹³C = 84.8 ± 3.2 in C2H2 and 89.8 ± 7.3 in C2H6, a possible trend of increasingly value with molecular mass, although these values are both compatible with the Huygens GCMS value to within error bars. There are no convincing trends in latitude. Combining all fifteen measurements, we obtain a value of ¹²C / ¹³C = 80.8 ± 2.0, also compatible with GCMS. Therefore, the evidence is mounting that ¹²C/¹³C is some 8% lower on Titan than on the Earth (88.9, inorganic standard), and lower than typical for the outer planets (88 ± 7 [Sada, P.V., McCabe, G.H., Bjoraker, G.L., Jennings, D.E., Reuter, D.C., 1996. Astrophys. J. 472, 903-907]). There is no current model for this enrichment, and we discuss several mechanisms that may be at work. © 2008 Elsevier Inc. All rights reserved.

Abstract:

With the exception of in situ atmospheric probes, the most useful way to study the atmospheres of other planets is to observe their electromagnetic spectra through remote observations, either from ground-based telescopes or from spacecraft. Atmospheric properties most consistent with these observed spectra are then derived with retrieval models. All retrieval models attempt to extract the maximum amount of atmospheric information from finite sets of data, but while the problem to be solved is fundamentally the same for any planetary atmosphere, until now all such models have been assembled ad hoc to address data from individual missions. In this paper, we describe a new general-purpose retrieval model, Non-linear Optimal Estimator for MultivariatE Spectral analySIS (NEMESIS), which was originally developed to interpret observations of Saturn and Titan from the composite infrared spectrometer on board the NASA Cassini spacecraft. NEMESIS has been constructed to be generally applicable to any planetary atmosphere and can be applied from the visible/near-infrared right out to microwave wavelengths, modelling both reflected sunlight and thermal emission in either scattering or non-scattering conditions. NEMESIS has now been successfully applied to the analysis of data from many planetary missions and also ground-based observations. © 2007 Elsevier Ltd. All rights reserved.