Exoplanet atmospheres

Abstract:

Jupiter’s Oval BA undergoes recurrent colour changes whose physical origin remains uncertain. Radiative transfer retrievals indicate that these changes occur in the upper chromophore haze of the vortex annulus, around and above the 0.2–bar level, and are primarily associated with a decrease in optical depth, with no significant change in particle size or haze altitude. We apply a one-dimensional microphysical model to this haze layer, constrained by the retrieved aerosol properties of the red annulus in 2016 and the whiter annulus in 2020, and use it to reproduce the observed colour-change timescale of approximately 0.5 years. Our results indicate that this transition is best reproduced by changes in tropospheric vertical transport within a subsiding annulus, corresponding to preferred downwelling velocities of order 10−4–10−3 m s−1 at chromophore-bearing pressures. These small vertical velocities may help explain why no clear dynamical signature has yet been identified.

Abstract:

In just over 3 yr of operation, JWST has observed all seven planets of the TRAPPIST-1 system. The two innermost planets were found to have little to no atmosphere, barring the presence of high-altitude aerosols. Here we present the first JWST transit spectra of the habitable-zone exoplanet TRAPPIST-1 f, which were obtained with NIRISS SOSS over the course of five transits. At least one stellar flare occurred in each visit, but unlike observations of closer-in TRAPPIST-1 planets, no evidence for contamination of the transit spectra from unocculted stellar surface heterogeneities was found. This nondetection does not guarantee the absence of unocculted heterogeneities in all future transit observations of this planet, and it could be explained by the transit chord of TRAPPIST-1 f having properties similar to the average, out-of-transit, visible stellar hemisphere at the time of observation. The transit spectra exhibit slopes ranging from −365 ppm μm−1 down to 15 ppm μm−1, which we attribute to stellar variability, that is, flares and/or smaller-scale events. The visits least affected by flares rule out H2/He-dominated atmospheres with surface pressures higher than about 20 mbar at 95% confidence. For high-mean-molecular-mass atmospheres, the exact upper limits on surface pressures depend on the reduction pipeline and on the treatment of the residual slopes in the transit spectra.

Abstract:

We report the JWST NIRSpec/PRISM transit spectrum of TOI-6894 b, an exceptional 420 K sub-Saturn that is one of the rare giant planets transiting a late M dwarf. Remarkably, both the light curve and the transit spectrum exhibit almost no stellar contamination. The spectrum is dominated by prominent absorption features from CH4 and the photochemical product CS2. For the first time in a transit spectrum, NH3 is visually evident, while subtler features from H2O and CO2 can also be seen. We significantly improve upon state-of-the-art photochemical reaction networks, and use our new network to run radiative-convective photochemical (“RCP”) models at different metallicities. These models show that the spectrum—in particular the size of the NH3 and CO2 features relative to the CH4 and H2O features—is most consistent with a metallicity of 3–10× solar. Using a semi-free retrieval framework that perturbs the RCP model’s abundance and temperature profiles to fit the data, we find that the planet’s C/O, N/O, and S/O ratios are consistent with solar values. A grid retrieval on 1D RCP equilibrium models reveals a similar result: [M/H] = 0.46 ± 0.08 and C/O = 0.69 ± 0.06. The planet’s atmospheric metallicity, abundance ratios, and bulk metal fraction are all strikingly similar to those of Jupiter, Saturn, and other gas giant exoplanets, despite orbiting a very low-mass star.

Abstract:

Sulfur chemistry has emerged as an important probe of exoplanet atmospheres in the JWST era, although observational constraints have thus far been largely limited to SO2 and H2S in warm and hot exoplanets. Recent JWST observations have revealed CS2 in several cooler gas giant exoplanets, yielding a new tracer of sulfur chemistry. However, the detailed chemical pathways responsible for the formation of CS2 remain poorly understood. Here, we use TOI-6894 b, a temperate gas giant with evidence for CS2, as a test case for one-dimensional photochemical kinetic-transport modeling and sensitivity analyses of CS2 chemistry. We show that CS2 is produced through coupled thermochemical and photochemical processes involving CH4 and H2S as the primary carbon and sulfur reservoirs, with S2 photolysis driving disequilibrium sulfur chemistry. Our models provide a physically consistent explanation for the observed CS2 feature in TOI-6894 b. Extending our analysis to gas giant exoplanets spanning a wide range of Teq, we find that CS2 abundance peaks in temperate to warm atmospheres (Teq ∼ 500–700 K), and declines toward both lower and higher temperatures. This temperature dependence provides a unified framework for interpreting current CS2 observations, accounting for reported detections in temperate to warm planets and the lack of detections in colder and hotter giant exoplanets. Our results establish CS2 as a complementary probe of sulfur inventories and atmospheric metallicity in cool gas giant exoplanets.