Exoplanet atmospheres

Abstract:

The origin of the red colouration in Jupiter's Great Red Spot (GRS) is a long-standing question in planetary science. While several candidate chromophores have been proposed, no clear conclusions have been reached regarding its nature, evolution, or relationship to atmospheric dynamics. In this work, we perform microphysical simulations of the reddish haze over the GRS and quantify the production rates and timescales required to sustain it. Matching the previously reported chromophore column mass and effective radius in the GRS requires column-integrated injection fluxes in the range 1×10⁻¹²–7×10⁻¹² kg m⁻² s⁻¹, under low upwelling velocities in the upper troposphere (v<inf>trop</inf>≲1.5×10⁻⁴ m s⁻¹) and particle charges of at least 20 electrons/μm. Such rates exceed the mass flux that standard photochemical models of Jupiter currently supply via NH<inf>3</inf>–C<inf>2</inf>H<inf>2</inf> photochemistry at 0.1–0.2 bar, the most popular chromophore pathway in recent literature. We find a lower limit of 7 years on the haze formation time. We also assess commonly used size and vertical distribution parameterisations for the chromophore haze, finding that eddy diffusion prevents the long-term confinement of a thin layer and that the extinction is dominated by particles that can be represented by a single log-normal size distribution.

Abstract:

The extreme conditions in Venus’s lower atmosphere make robust calibration of in situ observations challenging. Consequently, measurements from past entry probes provided mixed evidence regarding the existence of a near-surface particulate layer (NSPL). Although the Venera 11 (1978) and Venera 13 and 14 (1982) landers performed in situ spectrophotometric observations during descent, the original datasets were later lost. However, a subset has been reconstructed by digitising graphical outputs produced during the missions’ initial data-processing phase [1]. Following careful analysis to identify and mitigate errors and other artefacts, the reconstructed dataset retains the reliable downward-looking spectra acquired by the three landers from ~62 km altitude to the surface.Previous retrievals from the reconstructed Venera 13 indicated an NSPL centred at ~3.5–5 km, with particulate optical properties consistent with a basaltic composition [2]. Following the methodology of [2], we use NEMESIS, a radiative transfer and retrieval code [3], to perform near-surface retrievals from the reconstructed Venera 11 and Venera 14 datasets. The results from Venera 11, 13, and 14 retrievals are compared with reported detections and non-detections from other instruments on earlier in situ missions, to explore potential formation pathways for the NSPL in light of the combined observational record.References:[1] Ignatiev, N. I., Moroz, V. I., Moshkin, B. E., Ekonomov, A. P., Gnedykh, V. I., Grigor’ev, A. V., and Khatuntsev, I. V. Cosmic Research 35(1), 1–14 (1997).[2] Kulkarni, S. V., Irwin, P. G. J., Wilson, C. F., & Ignatiev, N. I. Journal of Geophysical Research: Planets, 130, e2024JE008728, (2025).[3] Irwin, P. G., Teanby, N. A., de Kok, R., Fletcher, L. N., Howett, C. J., Tsang, C. C., Wilson, C. F., Calcutt, S. B., Nixon, C. A., and Parrish, P. D. Journal of Quantitative Spectroscopy and Radiative Transfer 109(6), 1136–1150 (2008). 

Abstract:

Whether a planet's volcanic gas is oxidising or reducing is inherited from redox conditions in the planet's mantle. It is often presumed that reactions between iron species control mantle oxygen fugacity. However, iron alone need not be the sole dictator of how oxidising the interior of a planet is. Carbon is a powerful redox element, with great potential to feed back upon the mantle redox state as it melts. Despite Earth being carbon-poor, it has been proposed that the oxygen fugacity of Earth's upper mantle is in part controlled by carbon (Holloway et al., 1992; Stagno et al., 2013); a slightly-higher volatile endowment could make carbon-powered geochemistry inescapable. Indeed, a number of known rocky exoplanets are predicted to have formed with carbon contents greater than Earth (Bergin et al., 2023). We offer a framework for how carbon is transported from solid planetary interior to atmosphere, tracking redox couplings between carbon and iron. We also incorporate a coupled 1D energy- and mass-balance model to provide first-order predictions of the rate of volcanism. We show that carbon-iron redox coupling would maintain interior oxygen fugacity in a narrow range: more reducing than Earth magma, but not reducing enough to prevent CO2 outgassing entirely.Bergin, E. A., Kempton, E. M.-R., Hirschmann, M., Bastelberger, S. T., Teal, D. J., Blake, G. A., Ciesla, F. J., & Li, J. (2023). Exoplanet Volatile Carbon Content as a Natural Pathway for Haze Formation. The Astrophysical Journal, 949, L17. Holloway, J. R., Pan, V., & Gudmundsson, G. (1992). High-pressure fluid-absent melting experiments in the presence of graphite: Oxygen fugacity, ferric/ferrous ratio and dissolved CO2. European Journal of Mineralogy, 4(1), 105–114. Stagno, V., Ojwang, D. O., McCammon, C. A., & Frost, D. J. (2013). The oxidation state of the mantle and the extraction of carbon from Earth’s interior. Nature, 493(7430).

Abstract:

To extract, or 'retrieve' atmospheric properties from the observed radiance spectra from a planetary atmosphere requires software that can generate the expected radiances from a guessed atmospheric model, compare the radiances with those measured, determine how the model should be updated to reduce any discrepancy between the modelled and observed radiances, and then iterate these steps until these differences are minimised. One such retrieval model is NEMESIS (Nonlinear optimal Estimator for MultivariatE Spectral analySIS), which was initially developed by myself and my colleagues in the 1990s, and which has since been continually updated and enhanced. NEMESIS has now been used in more than 300 papers retrieving atmospheric properties from observed thermal and solar-reflected radiance spectra from all the planetary atmospheres in our solar system and also some beyond. NEMESIS uses the Optimal Estimation framework for atmospheric retrievals and is written in FORTRAN. Recently, more Bayesian frameworks have become computationally possible and favoured, especially for exoplanetary retrievals where prior constraints are almost entirely absent. Hence, NEMESIS has recently been updated to Python (ArchNEMESIS), and combined with PyMultiNest to allow nested sampling retrievals that can better explore the degeneracy between different atmospheric properties. I will review how NEMESIS retrievals have improved our understanding of planetary atmospheres over the last 30 years and how the development of ArchNEMESIS has breathed new life into the NEMESIS/ArchNEMESIS project.