Oxide electronics

Abstract:

The structural properties of BiMn$O_3$ were determined from neutron powder diffraction data as a function of temperature and magnetic field. The structure at all temperatures was found to be centrosymmetric with space group $C2/c$, which is incompatible with ferroelectricity. At T$_C\simeq 100 K$, we observed the onset of a large magnetoelastic strain, proportional to the square of the magnetization. We interpret this structural rearrangement, together with the previously observed magnetodielectric anomalies, as due to the need to optimize the partially frustrated magnetic interactions.

Abstract:

The detailed evolution of the magnitude of the local Jahn-Teller (JT) distortion in La(1-x)Ca(x)MnO3 is obtained across the phase diagram for 0< or =x< or =0.5 from high-quality neutron diffraction data using the atomic pair distribution function method. A local JT distortion is observed in the insulating phase for all Ca concentrations studied. However, in contrast with earlier local structure studies, its magnitude is not constant, but decreases continuously with increasing Ca content. This observation is at odds with a simple small-polaron picture for the insulating state.

Abstract:

The detailed evolution of the magnitude of the local Jahn-Teller (JT) distortion in La1-xCaxMnO3 is obtained across the phase diagram for 0≤x≤0.5 from high-quality neutron diffraction data using the atomic pair distribution function method. A local JT distortion is observed in the insulating phase for all Ca concentrations studied. However, in contrast with earlier local structure studies, its magnitude is not constant, but decreases continuously with increasing Ca content. This observation is at odds with a simple small-polaron picture for the insulating state. © 2007 The American Physical Society.

Abstract:

The structural and magnetic properties of the hexagonal four-layer form of SrMn O3 have been investigated by combining magnetization measurements, electron diffraction, and high-resolution synchrotron x-ray and neutron powder diffraction. Below 350 K, there is subtle structural phase transition from hexagonal symmetry (space group P 63/mmc) to orthorhombic symmetry (space group C 2221) where the hexagonal metric is preserved. The second-order phase transition involves a slight tilting of the corner-sharing Mn2 O9 units composed of two face-sharing Mn O6 octahedra and the associated displacement of Sr2+ cations. The phase transition is described in terms of symmetry-adapted displacement modes of the high symmetry phase. Upon further cooling, long range magnetic order with propagation vector k= (0,0,0) sets in below 300 K. The antiferromagnetic structure, analyzed using representation theory, shows a considerably reduced magnetic moment indicating the crucial role played by direct exchange between Mn centers of the Mn2 O9 units. © 2007 The American Physical Society.

Abstract:

Total scattering based atomic pair distribution function (PDF) analysis, with the advent of high data throughput neutron powder diffractometers, helps understanding the nature of the Jahn-Teller (JT) phase transition in La 1-xCaxMnO3 colossal magnetoresistive (CMR) manganites. The JT distortion of the MnO6 octahedra, is long-range ordered in the orthorhombic (O) phase, but disappears in the pseudo-cubic (O') phase crystallographically. An anomalous unit cell volume contraction occurs at the transition. The PDF study indicates that the distortion persists locally deep in the O' phase, contrary to the crystallographic view. Simultaneously, local structural features observed in PDF at 10.3 Å, sensitive to the oxygen sublattice changes, evolve dramatically across the transition. The same effect is observed irrespective of the way the O-O' phase boundary is crossed: it is seen both in the temperature series data for x=0, and in the doping series data at 310 K and at 550 K. © by Oldenbourg Wissenschaftsverlag.