Planetary surfaces

Abstract:

Hydrogen chloride (HCl) was recently discovered in the atmosphere of Mars by two spectrometers onboard the ExoMars Trace Gas Orbiter. The reported detection made in Martian Year 34 was transient, present several months after the global dust storm during the southern summer season. Here, we present the full data set of vertically resolved HCl detections obtained by the NOMAD instrument, which covers also Martian year 35. We show that the particular increase of HCl abundances in the southern summer season is annually repeated, and that the formation of HCl is independent from a global dust storm event. We also find that the vertical distribution of HCl is strikingly similar to that of water vapor, which suggests that the uptake by water ice clouds plays an important role. The observed rapid decrease of HCl abundances at the end of the southern summer would require a strong sink independent of photochemical loss.

Abstract:

Finding and characterizing extrasolar Earth analogs will rely on interpretation of the planetary system's environmental context. The total budget and fractionation between C-H-O species sensitively affect the climatic and geodynamic state of terrestrial worlds, but their main delivery channels are poorly constrained. We connect numerical models of volatile chemistry and pebble coagulation in the circumstellar disk with the internal compositional evolution of planetesimals during the primary accretion phase. Our simulations demonstrate that disk chemistry and degassing from planetesimals operate on comparable timescales and can fractionate the relative abundances of major water and carbon carriers by orders of magnitude. As a result, individual planetary systems with significant planetesimal processing display increased correlation in the volatile budget of planetary building blocks relative to no internal heating. Planetesimal processing in a subset of systems increases the variance of volatile contents across planetary systems. Our simulations thus suggest that exoplanetary atmospheric compositions may provide constraints on when a specific planet formed.