Space instrumentation

Abstract:

Context. The detection of sulphur species in the Martian atmosphere would be a strong indicator of volcanic outgassing from the surface of Mars.
Aims. We wish to establish the presence of SO2, H2S, or OCS in the Martian atmosphere or determine upper limits on their concentration in the absence of a detection.
Methods. We perform a comprehensive analysis of solar occultation data from the mid-infrared channel of the Atmospheric Chemistry Suite instrument, on board the ExoMars Trace Gas Orbiter, obtained during Martian years 34 and 35.
Results. For the most optimal sensitivity conditions, we determine 1σ upper limits of SO2 at 20 ppbv, H2S at 15 ppbv, and OCS at 0.4 ppbv; the last value is lower than any previous upper limits imposed on OCS in the literature. We find no evidence of any of these species above a 3σ confidence threshold. We therefore infer that passive volcanic outgassing of SO2 must be below 2 ktons day−1.

Abstract:

Ozone and water vapour volume mixing ratio vertical profiles in the Martian atmosphere derived from solar occultation mid-infrared spectra recorded by the Atmospheric Chemistry Suite on the ExoMars Trace Gas Orbiter. Data were recorded between mid Mars year 34 to early Mars year 36. Trace gas retrievals were done using the JPL Gas Fitting Software.

Abstract:

Temperature data derived from ACS NIR observations of Mars used in the paper: Seasonal changes in the vertical structure of ozone in the Martian lower atmosphere and its relationship to water vapour. LMD GCM data interpolated to the terminator (T/P/density/H2O/O3) used in the paper: Seasonal changes in the vertical structure of ozone in the Martian lower atmosphere and its relationship to water vapour.

Abstract:

Isotopic ratios in atmospheric CO2 are shaped by various processes throughout Mars' history, and can help understand what the atmosphere of early Mars was like to sustain liquid water on its surface. In this study, we monitor the O and C isotopic composition of CO2 between 70 and 130 km for more than half a Martian year using solar occultation observations by the Atmospheric Chemistry Suite onboard the ExoMars Trace Gas Orbiter. We find the vertical trends of the isotopic ratios to be consistent with the expectations from diffusive separation above the homopause, with average values below this altitude being consistent with Earth-like fractionation (δ13C = −3 ± 37‰; δ18O = −29 ± 38‰; and δ17O = −11 ± 41‰). Using these measurements, we estimate that at least 20%–40% of primordial C on Mars has escaped to space throughout history. The total amount of C lost from the atmosphere is likely to be well in excess of this lower limit, due to carbonate formation and further sink processes. In addition, we propose a photochemical transfer of light O from H2O to CO2 to explain the larger enrichment in the 18O/16O ratio in H2O than in CO2.