Quantification of carbonates, oxychlorines, and chlorine generated by heterogeneous electrochemistry induced by Martian dust activity
Geophysical Research Letters American Geophysical Union 50:4 (2023) e2022GL102127
Abstract:
Heterogeneous electrochemistry induced by Martian dust activity is an important type of atmosphere-surface interaction that affects geochemical processes at the Martian surface and in the Martian atmosphere. We have experimentally demonstrated that heterogeneous electrochemistry stimulated by mid-strength dust events can decompose common chloride salts, which is accompanied by the release of chlorine atoms into the atmosphere and the generation of (per)chlorates (chlorates and perchlorates) and carbonates. In this study, we present quantitative analyses on the above products from 26 heterogeneous electrochemical experiments on chloride salts. Based on these quantifications, our calculation indicates that such atmosphere-surface interaction during a portion of Amazonian period could accumulate the observed abundance of (per)chlorates, carbonates, and HCl by landed and orbital missions, and thus can be considered as a major driving force of the global chlorine-cycle on Mars. This study emphasizes the importance of measuring the electrical properties of dust activity on Mars.Venus, the Planet: Introduction to the Evolution of Earth’s Sister Planet
Space Science Reviews Springer Nature 219:1 (2023) 10
Venus Express
Chapter in Encyclopedia of Astrobiology Third Edition, (2023) 3171-3183
A two-Martian years survey of the water vapor saturation state on Mars based on ACS NIR/TGO occultations
Journal of Geophysical Research: Planets American Geophysical Union 128:1 (2022) e2022JE007348
Abstract:
On Mars, condensation is the major factor constraining the vertical distribution of water vapor. Recent measurements of water and temperature profiles showed that water can be strongly supersaturated at and above the level where clouds form during the aphelion and perihelion seasons. Since 2018, the near-infrared spectrometer (NIR) of the Atmospheric Chemistry Suite onboard the Trace Gas Orbiter has measured H2O and temperature profiles using solar occultation in the infrared from below 10 to 100 km of altitude. Here, we provide the first long-term monitoring of the water saturation state. The survey spans 2 Martian years from Ls = 163° of MY34 to Ls = 170° of MY36. We found that water is often supersaturated above aerosol layers. In the aphelion season, the water mixing ratio above 40 km in the mid-to-high latitudes was below 3 ppmv and yet is found to be supersaturated. Around the perihelion, water is also supersaturated above 60 km with a mixing ratio of 30–50 ppmv. Stronger saturation is observed during the dusty season in MY35 compared to what was observed in MY34 during the Global Dust Storm and around the perihelion. Saturation varied between the evening and morning terminators in response to temperature modulation imparted by thermal tides. Although water vapor is more abundant in the evening, colder morning temperatures induce a daily peak of saturation. This data set establishes a new paradigm for water vapor on Mars, revealing that supersaturation is nearly ubiquitous, particularly during the dust season, thereby promoting water escape on an annual average.Helene's surface properties from a photometric multi-wavelength analysis
Icarus Elsevier 392 (2022) 115376