Synthesis and crystal growth

Abstract:

The magnetic Bragg reflections of charge-stripe ordered La1.725Sr0.275NiO4 where investigated by neutron diffraction to determine the intensity ratio of first to third order harmonics. The third harmonic Bragg reflections were not observed at temperatures across that magnetically ordered phase, creating an upper bound for their intensity of 0.16% of the first harmonic intensity. © Published under licence by IOP Publishing Ltd.

Abstract:

Muon spin relaxation measurements are reported on three members of the LixMPO4 series. The magnetic properties of stoichiometric samples with M= Ni, Co, Fe were investigated at low temperature. In LiNiPO 4 we observe different forms of the muon decay asymmetry in the commensurate and incommensurate antiferromagnetic phases, accompanied by a change in the temperature dependence of the muon oscillation frequency. In LiCoPO4 the form of the muon decay asymmetry indicates that the correlation between layers decreases as the Néel temperature is approached from below. LiFePO4 shows more conventional behavior, typical for a three-dimensional antiferromagnet. Measurements on Li xFePO4 with x=0.8,0.9, and 1 show evidence for lithium diffusion below ∼250 K and muon diffusion dominating the form of the relaxation at higher temperature. The thermally activated form of the observed hopping rate suggests an activation barrier for lithium diffusion of ∼100 meV and a diffusion constant of DLi∼10-10to10 -9 cm2 s-1 at room temperature. © 2011 American Physical Society.

Abstract:

The magnetic ground states of the isostructural double perovskites Ba 2NaOsO6 and Ba2LiOsO6 are investigated with muon-spin relaxation. In Ba2NaOsO6 long-range magnetic order is detected via the onset of a spontaneous muon-spin precession signal below Tc=7.2±0.2K, while in Ba 2LiOsO6 a static but spatially disordered internal field is found below 8 K. A probabilistic argument is used to show from the observed precession frequencies that the magnetic ground state in Ba 2NaOsO6 is most likely to be low-moment (≈0.2μB) ferromagnetism and not canted antiferromagnetism. Ba2LiOsO6 is antiferromagnetic and we find a spin-flop transition at 5.5T. A reduced osmium moment is common to both compounds, probably arising from a combination of spin-orbit coupling and frustration. © 2011 American Physical Society.