Synthesis and crystal growth

Abstract:

Polarized- and unpolarized-neutron inelastic scattering has been used to measure the spin excitations in the striped spin-charge-ordered phase of La5/3Sr1/3NiO4. Above 30 meV, sharp magnetic modes are observed characteristic of a static stripe lattice. This part of the energy spectrum is described well by a linear spin-wave model with intrastripe and interstripe exchange interactions between neighboring Ni spins given by J = 15 ±1.5 meV and J′ = 7.5±1.5 meV, respectively. A pronounced suppression and broadening of the magnetic fluctuations in a band between 10 meV and 25 meV is suggestive of coupling to collective motions of the stripe domain walls.

Abstract:

Single crystals of ANb(2)O(6) (A = Nil Co, Fe, Mn) niobates have been grown by the floating-zone technique for the first time. The crystals were melt-grown from stoichiometric mixtures of the starting oxides. The orientation of the crystallographic axes relative to the crystal rod axis was found to be influenced by the size of the molten zone. Magnetization measurements as a function of temperature and applied field show that the magnetic properties are consistent with those found in previous studies. (C) 2002 Elsevier Science B.V. All rights reserved.

Abstract:

Large, high-quality crystals of undoped and Zn-doped CuO have been prepared successfully by the floating-zone technique. Formation Of Cu2O during the crystal growth of CuO has been eliminated under optimal growth conditions for the first time. The size of the grown crystals is typically 5-7 cm length and 8-9 turn in diameter, although with Zn doping the single crystal grains are found to form less readily. The Neel temperature is found to decrease with increasing Zn doping. Magnetic hysteresis measurements did not show any irreversible behaviour in either high purity ZnxCu1-xO crystals or polycrystalline CuO. (C) 2002 Elsevier Science B.V. All rights reserved.

Abstract:

We report a series of muSR measurements performed on single crystals of La1-x,SrxMnO3, (0 less than or equal to x less than or equal to 0.125) and on a polycrystalline bilayer manganite La2-2x Sr1+2xMn2O7 (v = 0.52). We find that the temperature dependence of the spinlattice relaxation rate is strongl, dependent on the hole doping and the associated changes in the magnetic structure. Y The systems have competing, anisotropic interactions, leading to a complex interplay of charge, spin and orbital order. This has a significant influence on the spin dynamics, both for perovskite and layered manganites. (C) 2002 Elsevier Science B.V. All rights reserved.

Abstract:

We report measurements and analysis of the magnetic critical phenomena in a single crystal of La0.875Sr0.125MnO3. The critical exponents associated with the ferromagnetic transition have been determined from ac susceptibility and dc magnetization data. Techniques like the Kouvel-Fischer plots, the modified Arrots plots, and the critical isotherm analysis were used for this purpose. The values of the exponents γ, β, and δ obtained are found to match very well with those predicted for the three-dimensional Heisenberg model. Our results are consistent with recent numerical calculations and suggest that though the double exchange interaction is driven by the motion of conduction electrons, the effective magnetic interaction near the transition is renormalized to a short range one. © 2003 The American Physical Society.