[Cu(HF2)2 (pyrazine)]n: a rectangular antiferromagnetic lattice with a spin exchange path made up of two different FHF- bridges.
Angew Chem Int Ed Engl 50:7 (2011) 1573-1576
[Cu(HF2)2(pyrazine)]n: A Rectangular Antiferromagnetic Lattice with a Spin Exchange Path Made Up of Two Different FHF− Bridges
Angewandte Chemie Wiley 123:7 (2011) 1611-1614
[Cu(HF2 )2 (pyz)]n : A rectangular antiferromagnetic lattice with a spin exchange path made up of two different FHF- bridges
Angewandte Chemie - International Edition 50:7 (2011) 1573-1576
Abstract:
The two-dimensional antiferromagnet [Cu(HF2)2(pyz)] n (pyz=pyrazine) has a rectangular lattice (see picture) displaying two types of FHF- bridging modes. The spin exchange through Cu-(FHF)2-Cu is about 90% stronger than through Cu-pyz-Cu, and the 1,1-coordinated FHF-, which is close in nature to F - ⋯ HF, is largely responsible for the exchange. C black, Cu red, F green, H cyan. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.[Cu(HF(2) )(2) (pyrazine)](n) : A Rectangular Antiferromagnetic Lattice with a Spin Exchange Path Made Up of Two Different FHF(-) Bridges.
Angew Chem Int Ed Engl (2011)
[Cu(HF2)2(pyrazine)]n: A Rectangular Antiferromagnetic Lattice with a Spin Exchange Path Made Up of Two Different FHF− Bridges
Angewandte Chemie Wiley (2011) n/a-n/a