Non-adiabatic small polaron hopping in the n = 3 ruddlesden-popper compound Ca4 Mn3 O10
Journal of Physics Condensed Matter 15:40 (2003) 6817-6833
Abstract:
Magnetotransport properties of the compound Ca4Mn3 O10 are interpreted in terms of activated hopping of small magnetic polarons in the non-adiabatic regime. Polarons are most probably formed around Mn3+ sites created by oxygen sub-stoichiometry. The application of an external field reduces the size of the magnetic contribution to the hopping barrier and thus produces an increase in the conductivity. We argue that the change in the effective activation energy around TN is due to the crossover to variable range hopping conduction as antiferromagnetic order sets in.Synthesis and characterisation of Sr1.2 Nd0.8 Mn0.6 Rh0.4 O4
Journal of Materials Chemistry 13:5 (2003) 1166-1172
Abstract:
A polycrystalline sample of Sr1.2Nd0.8Mn0.6Rh0.4O4 has been synthesised and characterised by neutron diffraction, dc magnetometry, muon spectroscopy and magnetotransport measurements. Ir is an n = 1 member of the Ruddlesden-Popper (RP) An + 1BnO3n + 1 family, having tetragonal (I4/mmm) symmetry [a = 3.86418(6), c = 12.4414(2) Å]. Rh and Mn cations are disordered over the six-coordinate sites within the perovskite layers of the RP structure and the A sites are occupied by a disordered distribution of Nd and Sr. In contrast to the analogous compound Sr1.2La 0.8Mn0.6Rh0.4O4, which showed long range ferromagnetic ordering in an applied field ar 2 K, a spin-glass transition was observed ar 16 K for the Nd-containing compound. No long range magnetic order was observed ar 2 K. A maximum magnetoresistance of ∼ 30% in a 140 kOe field was found at 125 K.Magnetotransport measurements on beta ''-(BEDT-TTF)(4)[(H3O)Ga3+(C2O4)(3)](center dot) C6N5NO2
SYNTHETIC MET 137:1-3 (2003) 1313-1314
Abstract:
Transport measurements have been carried out on single crystals of the charge transfer salt beta"-(BEDT-TTF)(4)[(H3O) Ga3+ (C2O4)(3)]. C6H5NO2, using magnetic fields of up to 33 T and temperatures down to 0.55 K. The material is found to be superconducting with T. 7.5 K and an in-plane critical field B-c2 greater than or equal to 33 T, and to exhibit Shubnikov-de Haas (SdH) oscillations. The temperature and angle dependence of the Shubnikov-de Haas oscillations and the upper critical field are reported, allowing information about the anisotropy of the upper critical field, effective mass m*, and the Fermi-surface (FS) of the material to be deduced.Magnetotransport measurements on β"-(BEDT-TTF)4 [(H3 O)Ga3+(C2 O4 )3 ]. C6 H5 NO2
Synthetic Metals 137:1-3 (2003) 1313-1314
Abstract:
Transport measurements have been carried out on single crystals of the charge transfer salt β″-(BEDT-TTF)4[(H3O)Ga3+(C2 O4)3]. C6H5NO2, using magnetic fields of up to 33 T and temperatures down to 0.55 K. The material is found to be superconducting with Tc ≈ 7.5 K and an in-plane critical field Bc2 ≥ 33 T, and to exhibit Shubnikov-de Haas (SdH) oscillations. The temperature and angle dependence of the Shubnikov-de Haas oscillations and the upper critical field are reported, allowing information about the anisotropy of the upper critical field, effective mass m*, and the Fermi-surface (FS) of the material to be deduced.Millimetre-wave response of the novel organic superconductors beta ''-ET4[(H3O)M(C2O4)(3)]center dot S (M=Fe3+, S=C6H5CN and C6H5NO2)
SYNTHETIC MET 137:1-3 (2003) 1225-1226