Prof Laura Herz FRS

Abstract:

Oligo-p-phenylenevinylene (OPV) materials monofunctionalised with ureido-s-triazine form chiral, helical stacks in dodecane solution. Here, we investigate resonance energy transfer dynamics in supramolecular stacks of OPVs consisting of three phenyl rings (MOPV3) doped with similar oligomers containing four phenyl rings (MOPV4). Broad spectral overlap between the MOPV3 fluorophores and MOPV4 chromophores results in efficient energy transfer from MOPV3 to MOPV4. We observe resonance energy transfer following two distinct regimes. The first is evident by growth of MOPV4 photoluminescence on a timescale of similar to50 ps, mediated by rapid exciton diffusion in MOPV3 within the stack. In the second regime, dynamics of localised excitons on nanosecond timescales are dominated by direct resonance energy transfer to MOPV4 chromophores. Global analysis of the photoluminescence decay of MOPV3 in blends with varying MOPV4 composition on times greater than or similar to2 ns is consistent with quasi-one-dimensional resonance energy transfer with Forster radius of 8 nm. (C) 2004 Elsevier B.V. All rights reserved.

Abstract:

We have demonstrated that it is possible to program pi-conjugated molecules to self-assemble into cylindrical aggregates in solution. By incorporating energy or electron traps in our stacks, energy and electron transfer processes in these one-dimensional assemblies have been studied in solution. The transfer of the single OPV cylinders from solution to a solid support as isolated objects was only possible when specific concentrations and specific solid supports were used. So far, however, we have not been able to measure any current through our fibers. (C) 2004 Elsevier B.V All rights reserved.