Prof. Patrick Irwin

Abstract:

All rights reserved.We present sub-millimeter spectra of HCN isotopologues on Titan, derived from publicly available ALMA flux calibration observations of Titan taken in early 2014. We report the detection of a new HCN isotopologue on Titan, H13C15N, and confirm an earlier report of detection of DCN. We model high signal-to-noise observations of HCN, H13CN, HC15N, DCN, and H13C15N to derive abundances and infer the following isotopic ratios: 12C/13C = 89.8 ±2.8, 14N/15N = 72.3 ±2.2, D/H = (2.5 ± 0.2) ×10-4, and HCN/H13C15N = 5800 ±270 (1σ errors). The carbon and nitrogen ratios are consistent with and improve on the precision of previous results, confirming a factor of ∼2.3 elevation in 14N/15N in HCN compared to N2 and a lack of fractionation in 12C/13C from the protosolar value. This is the first published measurement of D/H in a nitrile species on Titan, and we find evidence for a factor of ∼2 deuterium enrichment in hydrogen cyanide compared to methane. The isotopic ratios we derive may be used as constraints for future models to better understand the fractionation processes occurring in Titan's atmosphere.

Abstract:

The phase function describes the way particles scatter the incoming radiation. This is a fundamental piece of knowledge in order to understand how a planetary atmosphere scatters sunlight and so it has a profound influence in the retrieved atmospheric properties such as cloud height, particle density distribution and radiative forcing by aerosols. In this work we analyze data from the Imaging Science Subsystem (ISS) instrument onboard Cassini spacecraft to determine the particle phase function at blue (451 nm) and near infrared wavelengths (727-890 nm) of particles in the upper troposphere, where most of the incoming visible sunlight is scattered. In order to do so, we use observations taken in later 2010 and 2011 covering a broad range of phase angles from ~10° to ~160° in the blue (BL1) and near infrared filters associated with intermediate and deep methane absorption bands (MT2, CB2, MT3). Particles at all latitudes are found to be strongly forward scattering. The equatorial particles are in good agreement with laboratory measurements of 10 μm ammonia ice crystals, while mid- and sub-polar latitude particles may be similar to the equatorial particles, but they may also be consistent with 1 μm ellipsoids with moderate aspect ratios. Uncertainties due to limited phase coverage and parameter degeneracy prevent strong constraints of the particle shapes and sizes at these locations. Results for the particle phase function are also used to describe the spatial distribution of tropospheric particles both vertically and latitudinally in the Northern hemisphere.

Abstract:

The design of a versatile dual-telescope thermal-infrared radiometer spanning the spectral wavelength range 8–200 µm, in five spectral pass bands, for outer planet fly-by missions is described. The dual-telescope design switches between a narrow-field-of-view and a wide-field-of-view to provide optimal spatial resolution images within a range of spacecraft encounters to the target. The switchable dual-field-of-view system uses an optical configuration based on the axial rotation of a source-select mirror along the optical axis. The optical design, spectral performance, radiometric accuracy, and retrieval estimates of the instrument are discussed. This is followed by an assessment of the surface coverage performance at various spatial resolutions by using the planned NASA Europa Mission 13-F7 fly-by trajectories as a case study.

Abstract:

We use high-resolution ground-based observations from the VLT CRIRES instrument in November 2012 to identify sixteen previously undetected H3+ emission lines from Jupiter’s ionosphere. These emission lines are located in Jupiter’s 5-micron window (4.5−5.2 μm), an optically-thin region of the planet’s spectrum where the radiation mostly originates from the deep troposphere. The H3+ emission lines are so strong that they are visible even against this bright background. We measure the Doppler broadening of the H3+ emission lines in order to evaluate the kinetic temperature of the molecules, and we obtain a value of 1390 ± 160 K. We also measure the relative intensities of lines in the ν2 fundamental in order to calculate the rotational temperature, obtaining a value of 960 ± 40 K. Finally, we use the detection of an emission line from the 2ν2(2)-ν2 overtone to measure a vibrational temperature of 925 ± 25 K. We use these three independent temperature estimates to discuss the thermodynamic equilibrium of Jupiter’s ionosphere.

Abstract:

We report interferometric observations of carbon monoxide (CO) and its isotopologues in Titan's atmosphere using the Atacama Large Millimeter/submillimeter Array (ALMA). The following transitions were detected: CO (J = 1-0, 2-1, 3-2, 6-5), 13CO (J = 2-1, 3-2, 6-5), C18O (J = 2-1, 3-2), and C17O (J = 3-2). Molecular abundances and the vertical atmospheric temperature profile were derived by modeling the observed emission line profiles using NEMESIS, a line-by-line radiative transfer code. We present the first spectroscopic detection of 17O in the outer solar system with C17O detected at >8σ confidence. The abundance of CO was determined to be 49.6 ± 1.8 ppm, assumed to be constant with altitude, with isotopic ratios 12C/13C = 89.9 ± 3.4, 16O/18O = 486 ± 22, and 16O/17O = 2917 ± 359. The measurements of 12C/13C and 16O/18O ratios are the most precise values obtained in Titan's atmospheric CO to date. Our results are in good agreement with previous studies and suggest no significant deviations from standard terrestrial isotopic ratios.