Detection of hydrogen sulfide above the clouds in Uranus’s atmosphere
Nature Astronomy Nature Publishing Group 2:2018 (2018) 420-427
Abstract:
Visible-to-near-infrared observations indicate that the cloud top of the main cloud deck on Uranus lies at a pressure level of between 1.2 bar and 3 bar. However, its composition has never been unambiguously identified, although it is widely assumed to be composed primarily of either ammonia or hydrogen sulfide (H2S) ice. Here, we present evidence of a clear detection of gaseous H2S above this cloud deck in the wavelength region 1.57–1.59 μm with a mole fraction of 0.4–0.8 ppm at the cloud top. Its detection constrains the deep bulk sulfur/nitrogen abundance to exceed unity (>4.4–5.0 times the solar value) in Uranus’s bulk atmosphere, and places a lower limit on the mole fraction of H2S below the observed cloud of (1.0−2.5)×10−5. The detection of gaseous H2S at these pressure levels adds to the weight of evidence that the principal constituent of 1.2–3-bar cloud is likely to be H2S ice.2.5-D retrieval of atmospheric properties from exoplanet phase curves: Application to WASP-43b observations
Monthly Notices of the Royal Astronomical Society Oxford University Press (OUP)
Abstract:
We present a novel retrieval technique that attempts to model phase curve observations of exoplanets more realistically and reliably, which we call the 2.5-dimension (2.5-D) approach. In our 2.5-D approach we retrieve the vertical temperature profile and mean gaseous abundance of a planet at all longitudes and latitudes \textbf{simultaneously}, assuming that the temperature or composition, $x$, at a particular longitude and latitude $(\Lambda,\Phi)$ is given by $x(\Lambda,\Phi) = \bar{x} + (x(\Lambda,0) - \bar{x})\cos^n\Phi$, where $\bar{x}$ is the mean of the morning and evening terminator values of $x(\Lambda,0)$, and $n$ is an assumed coefficient. We compare our new 2.5-D scheme with the more traditional 1-D approach, which assumes the same temperature profile and gaseous abundances at all points on the visible disc of a planet for each individual phase observation, using a set of synthetic phase curves generated from a GCM-based simulation. We find that our 2.5-D model fits these data more realistically than the 1-D approach, confining the hotter regions of the planet more closely to the dayside. We then apply both models to WASP-43b phase curve observations of HST/WFC3 and Spitzer/IRAC. We find that the dayside of WASP-43b is apparently much hotter than the nightside and show that this could be explained by the presence of a thick cloud on the nightside with a cloud top at pressure $< 0.2$ bar. We further show that while the mole fraction of water vapour is reasonably well constrained to $(1-10)\times10^{-4}$, the abundance of CO is very difficult to constrain with these data since it is degenerate with temperature and prone to possible systematic radiometric differences between the HST/WFC3 and Spitzer/IRAC observations. Hence, it is difficult to reliably constrain C/O.Latitudinal variation in the abundance of methane (CH4) above the clouds in Neptune's atmosphere from VLT/MUSE Narrow Field Mode Observations
Icarus Elsevier 331 (2019) 69-82
Abstract:
Observations of Neptune, made in 2018 using the new Narrow Field Adaptive Optics mode of the Multi Unit Spectroscopic Explorer (MUSE) instrument at the Very Large Telescope (VLT) from 0.48 to 0.93 μm, are analysed here to determine the latitudinal and vertical distribution of cloud opacity and methane abundance in Neptune's observable troposphere (0.1–∼ 3bar). Previous observations at these wavelengths in 2003 by HST/STIS (Karkoschka and Tomasko 2011, Icarus 205, 674–694) found that the mole fraction of methane above the cloud tops (at ∼ 2 bar) varied from ∼ 4% at equatorial latitudes to ∼ 2% at southern polar latitudes, by comparing the observed reflectivity at wavelengths near 825 nm controlled primarily by either methane absorption or H2–H2/H2–He collision-induced absorption. We find a similar variation in cloud-top methane abundance in 2018, which suggests that this depletion of methane towards Neptune's pole is potentially a long-lived feature, indicative of long-term upwelling at mid-equatorial latitudes and subsidence near the poles. By analysing these MUSE observations along the central meridian with a retrieval model, we demonstrate that a broad boundary between the nominal and depleted methane abundances occurs at between 20 and 40°S. We also find a small depletion of methane near the equator, perhaps indicating subsidence there, and a local enhancement near 60–70°S, which we suggest may be associated with South Polar Features (SPFs) seen in Neptune's atmosphere at these latitudes. Finally, by the use of both a reflectivity analysis and a principal component analysis, we demonstrate that this depletion of methane towards the pole is apparent at all locations on Neptune's disc, and not just along its central meridian.Analysis of gaseous ammonia (NH3) absorption in the visible spectrum of Jupiter - Update
Icarus Elsevier 321 (2018) 572-582
Abstract:
An analysis of currently available ammonia (NH3) visible-to-near-infrared gas absorption data was recently undertaken by Irwin et al. (2018) to help interpret Very Large Telescope (VLT) MUSE observations of Jupiter from 0.48–0.93 µm, made in support of the NASA/Juno mission. Since this analysis a newly revised set of ammonia line data, covering the previously poorly constrained range 0.5–0.833 µm, has been released by the ExoMol project, “C2018” (Coles et al., 2018), which demonstrates significant advantages over previously available data sets, and provides for the first time complete line data for the previously poorly constrained 5520- and 6475-Å bands of NH3. In this paper we compare spectra calculated using the ExoMol–C2018 data set (Coles et al., 2018) with spectra calculated from previous sources to demonstrate its advantages. We conclude that at the present time the ExoMol–C2018 dataset provides the most reliable ammonia absorption source for analysing low- to medium-resolution spectra of Jupiter in the visible/near-IR spectral range, but note that the data are less able to model high-resolution spectra owing to small, but significant inaccuracies in the line wavenumber estimates. This work is of significance not only for solar system planetary physics, but for future proposed observations of Jupiter-like planets orbiting other stars, such as with NASA’s planned Wide-Field Infrared Survey Telescope (WFIRST).Three-dimensional structure of thermal waves in Venus’ mesosphere from ground-based observations
Icarus Elsevier (2022) 115187