Prof. Patrick Irwin

Abstract:

Thin-film transmission spectra of ammonium hydrosulfide (NH4SH) ice and ammonia (NH3) ice between 1300 and 12,000 cm-1 were used to determine the ice's optical constants. The films were grown on a sapphire substrate, and a Fourier-transform spectrometer and a grating spectrometer were used together to record the spectra. Lambert's law was used to directly determine the imaginary component of the complex refractive indices; from this, the real component was derived using the Kramers-Kronig algorithm. It is shown that, contrary to what is expected, the optical constants determined for NH3 ice at 80 K are in good agreement with those in the cubic phase, rather than the metastable one. The phase of the NH4SH ice was observed to change from amorphous to polycrystalline as the film was annealed to 160 K. © 2006 Optical Society of America.

Abstract:

The upper jovian atmosphere is particularly transparent at wavelengths near 5 μ m. Levels well below the cloud layers, which are situated between 0.5 and 2 bar, can be sounded. Large spatial variations of the brightness are observed, which are directly related to the opacity of the overlying cloud layer. Yet, the nature of the 5- μ m absorber in the jovian atmosphere has been subject of much debate. The cloud layer has been modelled many times as a thin, non-scattering layer, the opacity adjusted to fit the overall radiance level. This has proven to work well for individual spectra. Data from the Galileo near infrared mapping spectrometer (NIMS), covering the 0.7- 5.2 μ m range, include a number of observations of the same areas, separated by several hours, at different emission angles. Should the 5 μ m absorber be a thin absorbing layer then, apart from a change in radiance level, the overall shape of the 5- μ m spectrum is also expected to change significantly with emission angle. However, comparison of the 5- μ m spectra measured by NIMS of the same location but at different viewing angles reveals that while the overall radiance level decreases with increasing emission angle, the shape of the spectra remain unchanged. In this paper we present atmospheric models that include scattering to explain this effect. We show that the 5- μ m absorbing cloud particles must be significantly scattering ( ω = 0.9 ± 0.05 ) in order to explain these observations, and find that the base of the cloud layer must reside at pressures less than 2 bar. Furthermore, we show that the scattering within this cloud has important consequences on the retrieval of gas abundances from spectra in the 5- μ m region. © 2006 Elsevier Ltd. All rights reserved.