Hans Kraus

Abstract:

This study provides a comprehensive analysis of the electronic structure, reflectivity, and luminescent spectra of the organic-inorganic, metal-halide MAPbCl3 perovskite, which has considerable potential for various optoelectronic applications. Using density functional theory (DFT) calculations, we investigated the electronic structure of MAPbCl3 and interpreted the key features of its reflectivity spectra across a wide energy range from 3 to 10 eV. The reflectivity spectra reveal prominent excitonic features at 3.22 eV near the absorption edge and additional optical transitions at higher energies, highlighting the material’s intricate electronic structure. Furthermore, we examined the temperature dependence of radiative decay dynamics under high-energy radiation through X-ray luminescence spectra and decay time measurements. We observe emission from free and bound excitons with an exceptionally short decay time (≤ 1 ns) and significant thermal quenching at low temperatures (100 K) in the 385–430 nm range. These findings underline the importance of continued exploration of optoelectronic properties of the material to enhance its performance in practical applications.

Abstract:

Λ-Cold Dark Matter (ΛCDM) has been successful at explaining the large-scale structures in the universe but faces severe issues on smaller scales when compared to observations. Introducing self-interactions between dark matter particles claims to provide a solution to the small-scale issues in the ΛCDM simulations while being consistent with the observations at large scales. The existence of the energy region in which these self-interactions between dark matter particles come close to saturating the S-wave unitarity bound can result in the formation of dark matter bound states called darkonium. In this scenario, all the low energy scattering properties are determined by a single parameter, the inverse scattering length γ. In this work, we set bounds on γ by studying the impact of darkonium on the observations at direct detection experiments using data from CRESST-III and XENON1T. The exclusion limits on γ are then subsequently converted to exclusion limits on the self-interaction cross-section and compared with the constraints from astrophysics and N-body simulations.