Thermal structure of the middle and upper atmosphere of Mars From ACS/TGO CO2 spectroscopy
Journal of Geophysical Research: Planets American Geophysical Union 127:10 (2022)
Abstract:
Temperature and density in the upper Martian atmosphere, above ∼100 km, are key diagnostic parameters to study processes of the species' escape, investigate the impact of solar activity, model the atmospheric circulation, and plan spacecraft descent or aerobraking maneuvers. In this paper, we report vertical profiling of carbon dioxide (CO2) density and temperature from the Atmospheric Chemistry Suite (ACS) solar occultations onboard the ExoMars Trace Gas Orbiter. A strong CO2 absorption band near 2.7 μm observed by the middle infrared spectrometric channel (ACS MIR) allows the retrieval of the atmospheric thermal structure in an unprecedentedly large altitude range, from 20 to 180 km. We present the latitudinal and seasonal climatology of the thermal structure for 1.5 Martian years (MYs), from the middle of MY 34 to the end of MY 35. The results show the variability of distinct atmospheric layers, such as a mesopause (derived from 70 to 145 km) and homopause, changing from 90 to 100 km at aphelion to 120–130 km at perihelion. Some short-term homopause fluctuations are also observed depending on the dust activity.Climatology of the CO vertical distribution on Mars based on ACS TGO measurements
Journal of Geophysical Research: Planets American Geophysical Union 127:9 (2022) e2022JE007195
Abstract:
Carbon monoxide is a non-condensable gas in the Martian atmosphere produced by the photolysis of CO2. Its abundance responds to the condensation and sublimation of CO2 from the polar caps, resulting in seasonal variations of the CO mixing ratio. ACS onboard the ExoMars Trace Gas Orbiter have measured CO in infrared bands by solar occultation. Here we provide the first long-term monitoring of the CO vertical distribution at the altitude range from 0 to 80 km for 1.5 Martian years from Ls = 163° of MY34 to the end of MY35. We obtained a mean CO mixing ratio of ∼960 ppmv at latitudes from 45°S to 45°N and altitudes below 40 km, mostly consistent with previous observations. We found a strong enrichment of CO near the surface at Ls = 100–200° in high southern latitudes with a layer of 3,000–4,000 ppmv, corresponding to local depletion of CO2. At equinoxes we found an increase of the CO mixing ratio above 50 km to 3,000–4,000 ppmv at high latitudes of both hemispheres explained by the downwelling flux of the Hadley circulation on Mars, which drags the CO enriched air. General circulation models tend to overestimate the intensity of this process, bringing too much CO. The observed minimum of CO in the high and mid-latitudes southern summer atmosphere amounts to 700–750 ppmv, agreeing with nadir measurements. During the global dust storm of MY34, when the H2O abundance peaks, we see less CO than during the calm MY35, suggesting an impact of HOx chemistry on the CO abundance.No detection of SO2, H2S, or OCS in the atmosphere of Mars from the first two Martian years of observations from TGO/ACS
Astronomy and Astrophysics EDP Sciences 658 (2022) A86
Abstract:
Context. The detection of sulphur species in the Martian atmosphere would be a strong indicator of volcanic outgassing from the surface of Mars.Aims. We wish to establish the presence of SO2, H2S, or OCS in the Martian atmosphere or determine upper limits on their concentration in the absence of a detection.
Methods. We perform a comprehensive analysis of solar occultation data from the mid-infrared channel of the Atmospheric Chemistry Suite instrument, on board the ExoMars Trace Gas Orbiter, obtained during Martian years 34 and 35.
Results. For the most optimal sensitivity conditions, we determine 1σ upper limits of SO2 at 20 ppbv, H2S at 15 ppbv, and OCS at 0.4 ppbv; the last value is lower than any previous upper limits imposed on OCS in the literature. We find no evidence of any of these species above a 3σ confidence threshold. We therefore infer that passive volcanic outgassing of SO2 must be below 2 ktons day−1.
Seasonal changes in the vertical structure of ozone in the Martian lower atmosphere and its relationship to water vapour.
University of Oxford (2022)
Abstract:
Ozone and water vapour volume mixing ratio vertical profiles in the Martian atmosphere derived from solar occultation mid-infrared spectra recorded by the Atmospheric Chemistry Suite on the ExoMars Trace Gas Orbiter. Data were recorded between mid Mars year 34 to early Mars year 36. Trace gas retrievals were done using the JPL Gas Fitting Software.Seasonal changes in the vertical structure of ozone in the Martian lower atmosphere and its relationship to water vapour - Temperature and GCM data used
University of Oxford (2022)